2,2-二氯-1,1,1,3,3,3-六氟丙烷合成路线 （共 67 条）
反应条件
hydrogen fluoride; chlorine; 2percentCo2O3/Cr2O3, fluorided
T=325°C; Product distribution / selectivity;
参考文献
E. I. DU PONT DE NEMOURS AND COMPANY
Patent: WO2008/54782 A1, 2008 ;
Location in patent: Page/Page column 15-17 ;
反应条件
hydrogen fluoride; chlorine; iron(III) chloride on activated carbon in gas
T=380°C; 1.7 h; var. temp., rate of the chlorofluoropopane; sev. chlorofluoropropanes; furth. reactions: in liquid phase with chlorine absorbed in antimony trifluoride at var. pressure; Product distribution;
参考文献
Kvicala, J.; Paleta, O.; Dedek, V.
Journal of Fluorine Chemistry, 1989 , vol. 43, p. 155 - 175
反应条件
in further solvent(s)
chlorination in CF2ClCFCl2 at -80°C;
参考文献
Mochalina, E. P.; Dyatkin, B. L.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1965 , p. 899 - 901
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1965 , p. 926 - 928
C.A., 1965 , vol. 63, p. 5515
反应条件
N,N-dimethyl-formamide
参考文献
L Knunyants,I. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1966 , p. 992 - 999
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1966 , p. 1038 - 1047
反应条件
hydrogen
T=100 - 500°C; P=735.572 - 6546.59 Torr; 0.000833333 - 0.00983333 h; Combinatorial reaction / High throughput screening (HTS);
参考文献
Hedrick, Vicki E.; Boggs, Janet K.; Brandstadter, Stephan M.; Cohn, Mitchel
Patent: US2005/38302 A1, 2005 ;
Location in patent: Page/Page column 3-14 ;
反应条件
hydrogen fluoride; Catalyst M-Chromium oxide
T=375 - 425°C; Product distribution / selectivity;
参考文献
E. I. du Pont de Nemours and Company
Patent: US6677493 B1, 2004 ;
Location in patent: Page column 7 ;
反应条件
hydrogen
T=100 - 500°C; P=735.572 - 6546.59 Torr; 0.000833333 - 0.00983333 h; Combinatorial reaction / High throughput screening (HTS);
参考文献
Hedrick, Vicki E.; Boggs, Janet K.; Brandstadter, Stephan M.; Cohn, Mitchel
Patent: US2005/38302 A1, 2005 ;
Location in patent: Page/Page column 3-14 ;
反应条件
hydrogen fluoride; 1percent Pd supported on fluorided alumina catalyst
T=125 - 300°C; P=760.051 Torr; 0.00833333 h; Gas phase; Product distribution / selectivity;
参考文献
E.I. DUPONT DE NEMOURS AND COMPANY
Patent: WO2005/37742 A1, 2005 ;
Location in patent: Page/Page column 16; 19 ;
反应条件
hydrogen fluoride; Catalyst M-Chromium oxide
T=375 - 425°C; Product distribution / selectivity;
参考文献
E. I. du Pont de Nemours and Company
Patent: US6677493 B1, 2004 ;
Location in patent: Page column 7 ;
反应条件
triethylsilane; meta-chloroperoxybenzoic acid
1) 25 deg C, 1 h, 2) 100 deg C, 12 h; Yield givenYields of byproduct given;
参考文献
Petrov, Viacheslav A.
Journal of Organic Chemistry, 1998 , vol. 63, # 21 p. 7294 - 7297
