1-(1-丙炔-1-基)环己烯合成路线 （共 21 条）
反应条件
1: HgO, Fe2(SO4)3, aq. H2SO4 2: H2 / Pt / ethanol View Scheme
参考文献
Favorskaya,I.A.; Auvinen,E.M.
Journal of Organic Chemistry USSR (English Translation), 1965 , vol. 1, p. 478 - 480
Zhurnal Organicheskoi Khimii, 1965 , vol. 1, p. 486 - 489
反应条件
n-butyllithium in tetrahydrofuran
T=20°C; 14 h;
参考文献
Shintani, Ryo; Okamoto, Kazuhiro; Hayashi, Tamio
Chemistry Letters, 2005 , vol. 34, # 9 art. no. CL-050872, p. 1294 - 1295
反应条件
t-Bu-XantPhos; dichloro bis(acetonitrile) palladium(II); potassium carbonate; cesium fluoride in toluene
T=100°C; 20 h; Inert atmosphere;
参考文献
Liu, Yan-Yun; Yang, Xu-Heng; Huang, Xiao-Cheng; Wei, Wen-Ting; Song, Ren-Jie; Li, Jin-Heng
Journal of Organic Chemistry, 2013 , vol. 78, # 20 p. 10421 - 10426
反应条件
lithium aluminium tetrahydride; copper(I) bromide in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=0°C;
参考文献
Delbecq, Francoise; Baudouy, Rene; Gore, Jacques
Journal of Chemical Research, Miniprint, 1980 , # 3 p. 971 - 979
反应条件
1: 86 percent / POCl3 / pyridine / Heating
2: 49 percent / FeCl3, Li, liquid ammonia / 12 h
View Scheme
参考文献
Inman, Wayne D.; Sanchez, Kenneth A. J.; Chaidez, Manuel A.; Paulson, Donald R.
Journal of Organic Chemistry, 1989 , vol. 54, # 20 p. 4872 - 4881
反应条件
1.1: pyridine; trichlorophosphate / 5 h / 0 - 20 °C / |Inert atmosphere
2.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C / |Inert atmosphere
2.2: 4 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Zhao, Tony S. N.; Yang, Yuzhu; Lessing, Timo; Szabo, Kalman J.
Journal of the American Chemical Society, 2014 , vol. 136, # 21 p. 7563 - 7566
参考文献
Olsson,L.-I. et al.
Acta Chemica Scandinavica (1947-1973), 1973 , vol. 27, p. 1629 - 1636
反应条件
sodium carbonate
T=-20 - 25°C; 18 h;
参考文献
Hanack, Michael; Schuhmacher, Werner; Kunzmann, Erich
Chemische Berichte, 1982 , vol. 115, # 4 p. 1467 - 1487
反应条件
sodium carbonate
T=-20 - 25°C; 16 h; Further byproducts given;
参考文献
Hanack, Michael; Schuhmacher, Werner; Kunzmann, Erich
Chemische Berichte, 1982 , vol. 115, # 4 p. 1467 - 1487
反应条件
sodium carbonate
T=-20 - 25°C; 18 h; Further byproducts given;
参考文献
Hanack, Michael; Schuhmacher, Werner; Kunzmann, Erich
Chemische Berichte, 1982 , vol. 115, # 4 p. 1467 - 1487
