1: 1-bromo-4-fluorobenzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.5 h; Inert atmosphere; 2: With indium(III) chloride in tetrahydrofuran; hexane T=-78 - 20°C; 4 h; Inert atmosphere; 3: cyclopent-2-enone With methanol; [RhCl(η2:η2-cycloocta-1,5-diene)]2; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in tetrahydrofuran; hexane T=110°C; Inert atmosphere;

4,4'-bis(trimethylaminomethyl)-2,2'-bipyridine dihydrobromide; tetrafluoroboric acid; Pd(NH3)2Cl2 in water T=80°C; pH=1; 24 h;

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