(NC5H4)2(CH2)2(1+) or (CH3NC5H4)2(1+) in water
Kinetics; investigation of redn. of cobalt(III) complex by viologen radicals in stopped-flow apparatus (25°C, buffered solns.); further radicals investigated: (NC5H3CH3)2(CH2)2(1+), (NC5H4)2(CH2)3(1+), (NC5H4)2(CH2)4(1+);; not isolated; react. is monitored by UV/Vis-spectroscopy;;
参考文献
Tsukahara, K.; Wilkins, R. G.
Inorganic Chemistry, 1985 , vol. 24, p. 3399 - 3402
oxalate or H2edta(2-) in not given
Kinetics; Irradiation (UV/VIS); under oxygen-free Ar atmosphere, 5-10 fold excess of Co(II)-complex,ionic strength 0.15 M,pH 5.8, laser flash photolysis (ambient temp.), quenching by oxalate or H2edta(2-); UV/VIS monitoring (560 nm);
参考文献
Zahir, Khurram; Espenson, James H.; Bakac, A.
Inorganic Chemistry, 1988 , vol. 27, p. 3144 - 3146
oxalate or H2edta(2-) in not given
Kinetics; Irradiation (UV/VIS); under oxygen-free Ar atmosphere, 5-10 fold excess of Co(III)-complex, ionic strength 0.15 M, pH 5.8, laser flash photolysis (ambient temp.), quenching by oxalate or H2edta(2-); UV/VIs monitoring (560 nm);
参考文献
Zahir, Khurram; Espenson, James H.; Bakac, A.
Inorganic Chemistry, 1988 , vol. 27, p. 3144 - 3146
oxalate or H2edta(2-) in not given
Kinetics; Irradiation (UV/VIS); under oxygen-free Ar atmosphere, 5-10 fold excess of Co(III)-complex, ionic strength 0.15M, pH 5.8, laser flash photolysis (ambient temp.), quenching by oxalate or H2edta(2-); UV/VIS monitoring (480 or 685 nm);
参考文献
Zahir, Khurram; Espenson, James H.; Bakac, A.
Inorganic Chemistry, 1988 , vol. 27, p. 3144 - 3146
oxalate or H2edta(2-) in not given
Kinetics; Irradiation (UV/VIS); under oxygen-free Ar atmosphere, 5-10 fold excess of Co(III)-complex, ionic strength 0.15 M, pH 5.8, laser flash photolysis (ambient temp.), quenching by oxalate or H2edta(2-); UV/VIS monitoring (440 nm);
参考文献
Zahir, Khurram; Espenson, James H.; Bakac, A.
Inorganic Chemistry, 1988 , vol. 27, p. 3144 - 3146
