2-苯基乙基-1-硼酸频哪醇酯合成路线 （共 56 条）
反应条件
CuI(N-heterocyclic carbene) in tetrahydrofuran 4 h; Heating; Title compound not separated from byproducts.;
参考文献
Chemistry - A European Journal, , vol. 13, # 9 p. 2614 - 2621
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C 1.2: 2 h / -78 °C / Inert atmosphere 1.3: -78 - 20 °C / Inert atmosphere 2.1: Schwartz's reagent / dichloromethane / 1 h / 20 °C / Inert atmosphere 2.2: Inert atmosphere 3.1: (η-1,5-cyclooctadiene) {[4(R),5(R)]-1-benzoyl-2-[(S)-2-diphenylphosphinoferrocenyl]-4,5-diphenyl-4,5-dihydro-1-imidazole} iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen / dichloromethane / 12 h / 50 °C / 3750.38 Torr View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 4 p. 1014 - 1018
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / -78 °C 1.2: 2 h / -78 °C / Inert atmosphere 1.3: -78 - 20 °C / Inert atmosphere 2.1: Schwartz's reagent / dichloromethane / 1 h / 20 °C / Inert atmosphere 2.2: Inert atmosphere 3.1: (η-1,5-cyclooctadiene) {[4(R),5(R)]-1-benzoyl-2-[(S)-2-diphenylphosphinoferrocenyl]-4,5-diphenyl-4,5-dihydro-1-imidazole} iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen / dichloromethane / 12 h / 50 °C / 3750.38 Torr View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 4 p. 1014 - 1018
反应条件
1.1: Schwartz's reagent / dichloromethane / 1 h / 20 °C / Inert atmosphere 1.2: Inert atmosphere 2.1: (η-1,5-cyclooctadiene) {[4(R),5(R)]-1-benzoyl-2-[(S)-2-diphenylphosphinoferrocenyl]-4,5-diphenyl-4,5-dihydro-1-imidazole} iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen / dichloromethane / 12 h / 50 °C / 3750.38 Torr View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 4 p. 1014 - 1018
参考文献
Angew. Chem., , vol. 51, p. 1014 - 1018
Angewandte Chemie, , vol. 124, p. 1038 - 1042
反应条件
1.1: Schwartz's reagent / tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: hydrogen; (C5H2N(C6H5))CH2CH2CH(O)P(C(CH3)3)2Ir(C8H12)(1+)*B(C8H3F6)4(1-)=(C5H2N(C6H5))CH2CH2CH(O)P(C(CH3)3)2Ir(C8H12)B(C8H3F6)4 / dichloromethane / 18 h / 50 °C / 22502.3 Torr View Scheme
参考文献
Tetrahedron, , vol. 70, # 16 p. 2654 - 2660
反应条件
bis(1,5-cyclooctadiene)-rhodium(I) tetrafluoroborate; josiphos in 1,2-dichloro-ethane 24 h; Product distribution; Further Variations:Reagents;
参考文献
Journal of the American Chemical Society, , vol. 126, # 30 p. 9200 - 9201
反应条件
RhCl(CO)(P(C6H5)3)2 in acetonitrile-D3; benzene-d6 (N2); addn. of mixt. of 0.67 equiv. of boron compd. and alkene deriv. tosoln. of 0.03 equiv. of rhodium compd. in 3:1 mixt. of benzene-d6 and a cetonitrile-d3, shaking, heating at 80°C for 5 d; monitoring by NMR and GC-MS;
参考文献
Dalton Transactions, , # 8 p. 1055 - 1064
反应条件
rhodium complex bound to sila-bond diphenylphosphine in tetrahydrofuran 18 h;
参考文献
Synlett, , # 3 p. 477 - 481
反应条件
1: With tert.-butyl lithium in toluene; pentane T=-78 - 20°C; 4 h; 2: With sodium hydroxide; dihydrogen peroxide in toluene; pentane 2 h; Further stages. Title compound not separated from byproducts.;
参考文献
Blakemore, Paul R.; Burge, Matthew S.
Journal of the American Chemical Society, 2007 , vol. 129, # 11 p. 3068 - 3069
