2′,4′,6′-三甲基苯乙酮合成路线 (共 135 条)
反应条件
iron(III) chloride; acetic acid; acetyl chloride T=70°C; kinetic studies on the strictly catalytic acetylation; apparent activation energie, other metal chlorides, var. temp., time and conc. of reagents; Product distributionThermodynamic data;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 54, # 5 p. 1288 - 1292
反应条件
cobalt(II)salen; sodium 1.) THF, -70 deg C, 3 h --> r.t. in 2 h; 2.) THF, ether, 3 h; Yield given. Multistep reaction;
参考文献
Tetrahedron, , vol. 37, p. 863 - 865
反应条件
water; perchloric acid T=25°C; Rate constant;
参考文献
Canadian Journal of Chemistry, , vol. 65, p. 441 - 444
参考文献
Journal of the American Chemical Society, , vol. 66, p. 2131
Journal of the American Chemical Society, , vol. 68, p. 1472,1474
参考文献
Journal of Organic Chemistry, , vol. 50, # 26 p. 5612 - 5615
反应条件
aluminium trichloride 1.) 0 deg C, 2.) 100 deg C, 6 h;
参考文献
Journal of Organic Chemistry, , vol. 49, # 17 p. 3180 - 3183
反应条件
(K-18-crown-6 ether) cyanide in tetrahydrofuran T=20°C; 8 h; Equilibrium constant;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 34, # 11 p. 2396 - 2399
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 11 p. 2585 - 2589
反应条件
water T=88°C; Product distributionRate constant;
参考文献
Journal of Organic Chemistry, , vol. 45, # 19 p. 3892 - 3902
参考文献
Journal of the American Chemical Society, , vol. 66, p. 2131
Journal of the American Chemical Society, , vol. 68, p. 1472,1474
反应条件
aluminium trichloride in chloroform T=18°C; 6 h; further solvents, times, temperatures, methyl substituted acetophenones and benzenes; Product distributionMechanism;
参考文献
Journal of Chemical Research, Miniprint, , # 7 p. 3001 - 3012