1: trimethyl-sulfonium iodide With sodium hydride in tetrahydrofuran; dimethyl sulfoxide; mineral oil T=20°C; 0.5 h; Schlenk techniqueInert atmosphere; 2: para-chloroacetophenone in tetrahydrofuran; dimethyl sulfoxide; mineral oil T=0 - 20°C; Inert atmosphereSchlenk technique;

potassium tert-butylate in dimethyl sulfoxide T=20°C; Inert atmosphere;

Oxonereg;; ethylenediaminetetraacetic acid; water; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; acetone in dimethylformaldehyde dimethyl acetal; acetonitrile 4 h;

1: With tetramethylene sulfide; styrene; N,N,N',N'-tetra-methylnaphthalene-1,8-diamine in dichloromethane T=20°C; Corey-Chaykovsky reaction; 0.416667 h; Inert atmosphere; 2: With 1-tert-butyl-2,2,4,4,4-pentakis(dimethylamino)-25,45-catenodi(phosphazene) in tetrahydrofuran; dichloromethane T=20°C; Corey-Chaykovsky reaction; Inert atmosphere;

in dimethyl sulfoxide T=20°C; Addition; 12.5 h;

1: 4-chlorostyrene oxide With sec.-butyllithium in tetrahydrofuran; hexane; cyclohexane T=-58°C; 0.000206667 h; flow microreactor; 2: methyl iodide in tetrahydrofuran; hexane; cyclohexane T=-58°C; 0.000555556 h; flow microreactor;

oxygen in chlorobenzene T=95°C; P=757.6 Torr; var. of temp., further addition of cumene, ΔEa; Product distributionKineticsThermodynamic data;

methanol; potassium hydroxide; sulfuric acid Multistep reaction;

sulfuric acid in water; tert-butyl alcohol Hydrolysis;

1: bis(cyclopentadienyl)dimethyltitanium / tetrahydrofuran / 36 h / Inert atmosphere; Reflux 2: water; potassium carbonate / tetrahydrofuran; acetone / 16 h / Inert atmosphere View Scheme