2-叠氮基-1-甲基-3-硝基苯合成路线 （共 5 条）
反应条件
1: toluene / 2 h / Heating 2: triethyl phosphite / ethanol / 0.5 h / Heating 3: N-bromosuccinimide; benzoyl peroxide / CCl4 / 18 h / Heating View Scheme
参考文献
Bioorganic and Medicinal Chemistry, , vol. 11, # 6 p. 899 - 908
反应条件
T=20°C; 168 h; PhotolysisNeat (no solvent);
参考文献
Leyva, Elisa; Gonzalez-Balderas, Regina M.; De Loera, Denisse A.; Jimenez-Catano, Rogelio
Tetrahedron Letters, 2012 , vol. 53, # 19 p. 2447 - 2449
反应条件
1: toluene / 2 h / Heating 2: triethyl phosphite / ethanol / 0.5 h / Heating View Scheme
参考文献
Deghati, Paymaneh Y. F.; Borghini, Alice; Van Den Nieuwendijk, Adrianus M. C. H.; Dissen-de Groote, Miriam; IJzerman, Adriaan P.
Bioorganic and Medicinal Chemistry, 2003 , vol. 11, # 6 p. 899 - 908
反应条件
1: 2-methyl-6-nitroazidobenzene With triphenylphosphine in diethyl ether T=20°C; 1 h; 2: isobutyraldehyde in chloroform aza-Wittig reaction; 144 h; Heating; 3: With carbon monoxide; 1,3-bis-(diphenylphosphino)propane; 1,10-phenanthroline monohydrate; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide T=70°C; P=4560.31 Torr; 21 h; Further stages.;
参考文献
Tetrahedron, , vol. 64, # 41 p. 9675 - 9684
反应条件
1: 40 percent / conc.H2SO4, AcOH, CrO3 / 3 h
2: 75 percent / aq.HCl / aq. ethanol / 0.75 h / Heating
View Scheme
参考文献
Visentin, Sonja; Amiel, Pascale; Fruttero, Roberta; Boschi, Donatella; Roussel, Christian; Giusta, Laura; Carbone, Emilio; Gasco, Alberto
Journal of Medicinal Chemistry, 1999 , vol. 42, # 8 p. 1422 - 1427
