2-甲基-5-己烯-2-醇合成路线 （共 29 条）
反应条件
1: HCl / 20 h / 0 °C 2: 1) Mg / THF 3: LiAlH4 / diethyl ether / 0 °C View Scheme
参考文献
Ashby, E. C.; DePriest, R. N.; Goel, A. B.; Wenderoth, Bernd; Pham, Tung N.
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3545 - 3556
反应条件
titanium(IV) isopropylate; iso-propylmagnesium bromide in diethyl ether T=20°C; Title compound not separated from byproducts;
参考文献
Isakov, Vladimir E.; Kulinkovich, Oleg G.
Synlett, 2003 , # 7 p. 967 - 970
反应条件
1: HCl / 20 h / 0 °C 2: 1) Mg / THF 3: LiAlH4 / diethyl ether / 0 °C 4: 6.6 g / Br2 / PPh3 / pyridine / 20 h / Heating 5: 7.5 percent Chromat. / LiAlH4 / tetrahydrofuran / 480 h / Ambient temperature View Scheme
参考文献
Ashby, E. C.; DePriest, R. N.; Goel, A. B.; Wenderoth, Bernd; Pham, Tung N.
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3545 - 3556
反应条件
(bipyH2)-CrOCl5 in dichloromethane 7 h; Heating;
参考文献
Chakraborty, T. K.; Chandrasekaran, S.
Chemistry Letters, 1985 , p. 551 - 554
反应条件
Celite; pyridinium chlorochromate in dichloromethane T=30°C; 6 h;
参考文献
Journal of Chemical Research, Miniprint, , p. 2213 - 2246
反应条件
hydrogenchloride in water 0.333333 h;
参考文献
Dragoli; Burdett; Ellman
Journal of the American Chemical Society, 2001 , vol. 123, # 41 p. 10127 - 10128
参考文献
Colonge; Lagier
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1947 , vol. 225, p. 1161
Bulletin de la Societe Chimique de France, 1949 , p. 28
反应条件
in diethyl ether
T=0°C;
参考文献
Dash, Jyotirmayee; Melillo, Bruno; Arseniyadis, Stellios; Cossy, Janine
Tetrahedron Letters, 2011 , vol. 52, # 17 p. 2246 - 2249
反应条件
in diethyl ether
1 h;
参考文献
Baskaran, Sundarababu; Islam, Imadul; Chandrasekaran, Srinivasan
Journal of Chemical Research, Miniprint, 1992 , p. 2213 - 2246
反应条件
magnesium in diethyl ether
5 h; Ambient temperature;
参考文献
Pirrung, Frank O. H.; Hiemstra, Henk; Speckamp, W. Nico; Kaptein, Bernard; Schoemaker, Hans E.
Tetrahedron, 1994 , vol. 50, # 43 p. 12415 - 12442
