4,4,5,5-四甲基-2- (4-苯基丁基)-1,3,2-二噁硼烷合成路线 (共 13 条)
反应条件
Wilkinson's catalyst in dichloromethane 25°C, 10 min;
参考文献
Journal of the American Chemical Society, , vol. 118, # 4 p. 909 - 910
反应条件
copper(l) iodide; tetra-(n-butyl)ammonium iodide; lithium tert-butylate in tetrahydrofuran T=60°C; 18 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 2 p. 528 - 532
反应条件
1: 3-phenyl-propionaldehyde; diazomethyl-trimethyl-silane With triphenylphosphine; isopropyl alcohol; Wilkinson's catalyst in tetrahydrofuran T=20°C; 2: pinacolborane in tetrahydrofuran T=20°C;
参考文献
Journal of Organometallic Chemistry, , vol. 690, # 23 p. 5198 - 5205
反应条件
triphenylphosphine; diazomethyl-trimethyl-silane; [rhodium(I)chloride(triphenylphosphine)3] in tetrahydrofuran; isopropyl alcohol (Ar); addn. of 2-propanol to soln. of RhCl(PPh3)3 and PPh3 in THF; addn.of hydrocinnamaldehyde and then trimethylsilyldiazomethane, evolution o f gas; stirring at room temp., TLC analysis; slow addn. of pinacolborane; stirring at room temp.; TLC analysis, not isolated;
参考文献
Journal of Organometallic Chemistry, , vol. 690, # 23 p. 5198 - 5205
反应条件
iron(II)(bis(2,6-Et2-phenyl-iminomethyl)pyridine) dichloride; (4-Methylphenyl)-magnesium bromide in tetrahydrofuran T=20°C; 1 h; Inert atmosphere;
参考文献
Chemical Communications, , vol. 49, # 95 p. 11230 - 11232
反应条件
iron(II)(bis(2,6-Et2-phenyl-iminomethyl)pyridine) dichloride in tetrahydrofuran T=20°C; 1 h; Inert atmosphere;
参考文献
Chemical Communications, , vol. 49, # 95 p. 11230 - 11232
反应条件
iron(II)(bis(2,6-Et2-phenyl-iminomethyl)pyridine) dichloride in tetrahydrofuran T=20°C; 1 h; Inert atmosphere;
参考文献
Chemical Communications, , vol. 49, # 95 p. 11230 - 11232
反应条件
iron(II)(bis(2,6-Et2-phenyl-iminomethyl)pyridine) dichloride in tetrahydrofuran T=20°C; 1 h; Inert atmosphere;
参考文献
Chemical Communications, , vol. 49, # 95 p. 11230 - 11232
反应条件
iron(II)(bis(2,6-Et2-phenyl-iminomethyl)pyridine) dichloride in tetrahydrofuran T=20°C; 1 h; Inert atmosphere;
参考文献
Chemical Communications, , vol. 49, # 95 p. 11230 - 11232
反应条件
1: 4-phenyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butane With n-butyllithium; zinc(II) chloride in tetrahydrofuran; hexane; dichloromethane 2: With sodium chlorite; dipotassium hydrogenphosphate in water; tert-butyl alcohol 3: diazomethane in hexane; dichloromethane T=20°C; 1 h;
参考文献
Lebel, Helene; Ladjel, Chehla
Journal of Organometallic Chemistry, 2005 , vol. 690, # 23 p. 5198 - 5205