1-苯基-乙酮 2-(2,4-二硝基苯基)腙合成路线 （共 27 条）
反应条件
1: 93 percent / m-chloroperbenzoic acid / CH2Cl2 / -23 °C 2: 84 percent / butyl-lithium / hexane; tetrahydrofuran / 0 °C 3: 85 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / Heating 4: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 195 - 204
反应条件
1: 95 percent / ethanol 2: 89 percent / butyl-lithium / tetrahydrofuran; hexane / 0 - 20 °C 3: 93 percent / m-chloroperbenzoic acid / CH2Cl2 / -23 °C 4: 84 percent / butyl-lithium / hexane; tetrahydrofuran / 0 °C 5: 85 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / Heating 6: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 195 - 204
反应条件
1: 74 percent / butyl-lithium / hexane; tetrahydrofuran / 1 h / 0 °C 2: 84 percent / butyl-lithium / hexane; tetrahydrofuran / 0 °C 3: 85 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / Heating 4: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 195 - 204
反应条件
1: 1.) lithium naphthalenide 2: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 195 - 204
反应条件
1: 60 percent / butyl-lithium / hexane; tetrahydrofuran / 1 h / 0 °C 2: 85 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / Heating 3: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 195 - 204
反应条件
1: m-chloroperbenzoic acid / CH2Cl2 2: 60 percent / butyl-lithium / hexane; tetrahydrofuran / 1 h / 0 °C 3: 85 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / Heating 4: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 195 - 204
反应条件
1: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 195 - 204
反应条件
1: 84 percent / butyl-lithium / hexane; tetrahydrofuran / 0 °C 2: 85 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / Heating 3: 85percent m-chloroperbenzoic acid / CH2Cl2 / 1.5 h / -23 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 195 - 204
反应条件
1: aq.-ethanolic ammonia; hydrazine hydrate View Scheme
参考文献
Analyst (Cambridge, United Kingdom), , vol. 61, p. 391,393
反应条件
KBrO3; hydrogenchloride; water 1) 65 deg C, 3 h, 2) Δ, 15 min; Yield given. Multistep reaction;
参考文献
Tetrahedron, , vol. 48, # 25 p. 5323 - 5330
