反应条件
HNO3; [Ru(2,2′-6′,2″-terpyridine)(2,2’-bipyridine)(H2O)](ClO4)2 in water
Kinetics; charging of the flask with (NH4)2Ce(NO3)6 in aq. HNO3 and purging with N2 for 20 min, injecting of aq. soln. of Ru(H2O)(tpy)(bipy)(ClO4)2, stirring at 30°C; evolution of gas; monitoring by ESI-MS and UV;
参考文献
Wasylenko, Derek J.; Ganesamoorthy, Chelladurai; Henderson, Matthew A.; Koivisto, Bryan D.; Osthoff, Hans D.; Berlinguette, Curtis P.
Journal of the American Chemical Society, 2010 , vol. 132, # 45 p. 16094 - 16106