4,4,5,5-四甲基-2-(2-甲基烯丙基)-1,3,2-二噁硼烷合成路线 (共 5 条)
反应条件
magnesium in tetrahydrofuran T=25°C; 2.08333 h; Inert atmosphere;
参考文献
Niyomchon, Supaporn; Audisio, Davide; Luparia, Marco; Maulide, Nuno
Organic Letters, 2013 , vol. 15, # 9 p. 2318 - 2321
反应条件
palladium dichloride in tetrahydrofuran T=60°C; 12 h;
参考文献
Zhang, Ping; Roundtree, Ian A.; Morken, James P.
Organic Letters, 2012 , vol. 14, # 6 p. 1416 - 1419
反应条件
[Pt(dba)2]; triphenyl-arsane; triethylamine in toluene T=50°C; borylation; 16 h;
参考文献
Murata, Miki; Watanabe, Shinji; Masuda, Yuzuru
Tetrahedron Letters, 2000 , vol. 41, # 31 p. 5877 - 5880
反应条件
tris-(dibenzylideneacetone)dipalladium(0) in dimethyl sulfoxide T=60°C; Miyaura reaction; 12 h; Inert atmosphere;
参考文献
Zhang, Ping; Brozek, Laura A.; Morken, James P.
Journal of the American Chemical Society, 2010 , vol. 132, # 31 p. 10686 - 10688
反应条件
1: With scandium tris(trifluoromethanesulfonate) in dichloromethane
T=-78°C; 16 h;
2: With diisobutylaluminium hydride in dichloromethane; toluene
T=-78°C; 0.5 h;
参考文献
Lachance, Hugo; Lu, Xiaosong; Gravel, Michel; Hall, Dennis G.
Journal of the American Chemical Society, 2003 , vol. 125, # 34 p. 10160 - 10161