AgNO3 in water byproducts: AgI; Pt-complex was suspended in water, AgNO3 in H2O was added, stirred for 2h at 50°C, filtered, NaCl in H2O was added, stirred for 30 min a t 50°C, cooled in refrigerator for 2 ds; elem. anal.;
参考文献
Arendse, Malcolm J.; Anderson, Gordon K.; Majola, Raquel N.; Rath, Nigam P.
Inorganica Chimica Acta, 2002 , vol. 340, p. 65 - 69
hydrogenchloride in water treatment of Pt-complex with ligand in aqueous soln. acidified with HCl; filtn., dissolving in dmf, reprecipitating by addn. of water and HCl, left to stand overnight;
silver sulphate in water byproducts: AgI; Ag:Pt=1.28:0.65 molar ratio, Pt compd. added to a soln. of Ag salt, stirred overnight at 40°C in the dark, filtered, KCl (excess) added, stored for 24 h; ppt. centrifuged, washed (cold water, ethanol, diethyl ether), dried (vac.);
in methanol Kinetics; reduction of Pt(IV)-complex by Pt(II)-complex in MeOH in the presence of chloride ions depending on temperature (25, 35, 45°C); monitored by UV-spectroscopy;
in methanol Kinetics; reduction of Pt(IV)-complex by Pt(II)-complex in MeOH in the presence of chloride ions depending on temperature (25, 35, 45°C); monitored by UV-spectroscopy;