三甲基-(三甲基锡烷基甲基)锡烷合成路线 （共 34 条）
反应条件
magnesium in diethyl ether
参考文献
Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.1, page 6 - 20
参考文献
Kraus; Neal
Journal of the American Chemical Society, 1930 , vol. 52, p. 696,698,699
反应条件
in diethyl ether; benzene
stirred overnight at room temp. then for 1 h at 40°C; water added, org. layer sepd., dried (MgSO4), distd. under reduced pressure;
参考文献
Bruin, J. W.; Schat, G.; Akkerman,O. S.; Bickelhaupt, F.
Journal of Organometallic Chemistry, 1985 , vol. 288, p. 13 - 26
反应条件
catalyst: Pd bis(dibenzylideneacetone)/P(OC2H5)3 in toluene
heating soln. of (CH3)3SnCCH (20 mmol) and CH2(Sn(CH3)2)4CH2 (10 mmol) in toluene for 30 h at 75°C in presence of palladium bis(dibenzylidene acetone) (3 molpercent) and P(OC2H5)3 (6 molpercent);; removing toluene under water-pump vac.; Kugelrohr distn. at 120°C/0.001 torr; formation of 3percent ((CH3)3Sn)2CH2 and 10percent (CH3)6Sn2 is observed;;
参考文献
Mitchell, T.N.; Kowall, B.
Journal of Organometallic Chemistry, 1992 , vol. 437, # 1/2 p. 127 - 130
反应条件
dichloromethane in tetrahydrofuran
参考文献
Mitchell, Terence N.; Fabisch, Bodo
Journal of Organometallic Chemistry, 1984 , vol. 269, # 3 p. 249 - 254
反应条件
lithium in tetrahydrofuran; water
O2-free atmosphere; Li (cuttings) and Me3SnCl in THF (25°C, 15 h), filtrate added to dibromobicyclooctadiene (THF, -78°C)(molar ratio 1.54), stirring (room temp.), poured into water, extn. (pentane), drying (Na2SO4);other products; monitored by (1)H-NMR;
参考文献
Hertkorn, N.; Koehler, F. H.
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1988 , vol. 43, # 11 p. 1405 - 1415
反应条件
magnesium in tetrahydrofuran
careful addn. of CHBr3 in dry THF to the Grignard reagent from Me3SnCl and Mg turnings; distd. at <0.8 mmHg, purified by crystn. from ethanol;
参考文献
Hawker, Darryl W.; Wells, Peter R.
Journal of Organometallic Chemistry, 1984 , vol. 266, # 1 p. 37 - 44
参考文献
Murayama, Eigoro; Kikuchi, Toshihiro; Sasaki, Kotaro; Sootome, Norio; Sato, Tadashi
Chemistry Letters, 1984 , p. 1897 - 1900
反应条件
byproducts: H2, CH4, C2H6; other Radiation; X-ray, 1.0 MeV, 77°K; not isolated, detected by ESR and MS;
参考文献
Hoeppner, K.; Lassmann, G.
Zeitschrift fuer Naturforschung, 1968 , vol. 23a, p. 1758 - 1762
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.1.4.2.1, page 46 - 46
Full Text Show Details
Hoeppner, K.
Proc. 2nd Tihany Symp. Radiat. Chem. Tihany, Hung., 1966 (1967), S. 33/6
反应条件
multistep reaction: cyclopropanol formation, other substrates, different equivalents; Mechanism;
参考文献
Sato, Tadashi; Kikuchi, Toshihiro; Tsujita, Hiroshi; Kaetsu, Atsushi; Sootome, Norio; Nishida, Ken-Ichiro; Tachibana, Kazutaka; Murayama, Eigoro
Tetrahedron, 1991 , vol. 47, # 20-21 p. 3281 - 3304
