N-对甲苯磺酰-3-吡咯啉合成路线 （共 32 条）
反应条件
(SPY-5-31)-dichloro-(κ2(C,O)-(2-isopropyloxybenzylidene))(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)ruthenium in deuterated toluene T=29.84°C; Reagent/catalyst;
参考文献
Chemistry - A European Journal, , vol. 19, # 48 p. 16403 - 16414
反应条件
copper(I) bromide in 1,4-dioxane T=110°C; 3 h;
参考文献
European Journal of Organic Chemistry, , vol. 2014, # 11 p. 2305 - 2311
反应条件
potassium fluoride; 3,4,7,8-tetra-methyl-1,10-phenanthroline; 2C7H7O3S(1-)*Cu(2+)*C6H6; para-toluenesulphonic acid silver salt; silver fluoride in N,N-dimethyl-formamide T=50°C; 24 h; GloveboxInert atmosphere;
参考文献
Xu, Jun; Xiao, Bin; Xie, Chuan-Qi; Luo, Dong-Fen; Liu, Lei; Fu, Yao
Angewandte Chemie - International Edition, 2012 , vol. 51, # 50 p. 12551 - 12554
Angew. Chem., 2012 , vol. 124, # 50 p. 12719 - 12722,4
反应条件
(H2IPr)Cl2Ru=CH(o-iPrOC6H3NO2) in methanol T=70°C; 1 h;
参考文献
Skowerski, Krzysztof; Bialecki, Jacek; Tracz, Andrzej; Olszewski, Tomasz K.
Green Chemistry, 2014 , vol. 16, # 3 p. 1125 - 1130
反应条件
[(.eta.6-p-cymene)Ru(P(cyclohexyl)3)(CCC(phenyl)2)Cl](PF6) in toluene T=80°C; Cyclization; Ring closing metathesis reaction; Product distribution; Further Variations:CatalystsReagents;
参考文献
Chemistry - A European Journal, , vol. 6, # 10 p. 1847 - 1857
反应条件
1: hydrogenchloride / ethanol / 20 - 80 °C 2: 2C7H7O3S(1-)*Cu(2+)*C6H6; 3,4,7,8-tetra-methyl-1,10-phenanthroline; silver fluoride; potassium fluoride; para-toluenesulphonic acid silver salt / N,N-dimethyl-formamide / 24 h / 50 °C / |Glovebox; |Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 50 p. 12551 - 12554
Angew. Chem., , vol. 124, # 50 p. 12719 - 12722,4
反应条件
2,3-dicyano-5,6-dichloro-p-benzoquinone in benzene T=110°C; 5 h; Inert atmosphere;
参考文献
Shin, Ye Ho; Maheswara, Muchchintala; Hwang, Joon Young; Kang, Eun Joo
European Journal of Organic Chemistry, 2014 , vol. 2014, # 11 p. 2305 - 2311
反应条件
1: 75 percent / NBS, H2O / dimethylsulfoxide 2: 81 percent / (n-Bu)3SnH / tetrahydrofuran / 5 h / Heating 3: 77 percent / PCC / CH2Cl2 / Ambient temperature View Scheme
参考文献
Kim, Wan-Joo; Kim, Bong-Jin; Lee, Tae-Suk; Nam, Keun-Soo; Kim, Keun-Jae
Heterocycles, 1995 , vol. 41, # 7 p. 1389 - 1398
反应条件
Oxonereg;; 1,1,1-trifluoropropanone; sodium hydrogencarbonate; (ethylenedinitrilo)tetraacetic acid disodium salt in water; acetonitrile T=0°C;
参考文献
Hodgson, David M.; Miles, Timothy J.; Witherington, Jason
Tetrahedron, 2003 , vol. 59, # 49 p. 9729 - 9742
反应条件
1: 75 percent / NBS, H2O / dimethylsulfoxide 2: 81 percent / (n-Bu)3SnH / tetrahydrofuran / 5 h / Heating 3: 77 percent / PCC / CH2Cl2 / Ambient temperature 4: Br2, AcOH / 0.08 h / 46 - 50 °C View Scheme
参考文献
Heterocycles, , vol. 41, # 7 p. 1389 - 1398
