sodium amide in ammonia treating o-carborane with NaNH2 in liq. NH3, methylation (molar ratio carborane:metal=1:0.5, 1:1.0 and 1.1.5); various product ratio;;
参考文献
Stanko, V. I.; Gol'tyapin, Yu. V.
Journal of General Chemistry USSR (English Translation), 1971 , vol. 41, p. 2053 - 2058
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Gmelin Handbook: B: B-Verb.11, 4.1, page 56 - 59
in ethanol under N2; mixt. of o-carborane and CsF (molar ratio 1:3) in EtOH stirredunder reflux for 20 h; cooled to room temp.; not isolated; detd. by (11)B NMR spectroscopy;
参考文献
Yoo; Hwang; Do
Inorganic Chemistry, 2001 , vol. 40, # 3 p. 568 - 570
in neat (no solvent)
thermal izomerization at 620-700 °C;; 52-53percent m-C2B10H12, 47-48percent p-C2B10H12;;
参考文献
Stanko, V. I.; Brattsev, V. A.; Gol'tyapin, Yu. V.
Doklady Akademii Nauk SSSR, 1976 , vol. 226/231, p. 1243 - 1246
Doklady Akademii Nauk SSSR, 1976 , vol. 231, p. 925 - 928
in neat (no solvent)
sublimation of o-C2B10H12 at 200-250 °C, passing sublimate with N2 (heated, purified) through heated tube into cooled vessel (200 mL/min, 0.25 g o-C2B10H12/min, contact time 0.34 min, 700 °C);
参考文献
Papetti, S.; Obenland, C.; Heying, Th. L.
Industrial and Engineering Chemistry Product Research and Development, 1966 , vol. 5, p. 334 - 337
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Gmelin Handbook: B: B-Verb.11, 2.2.2, page 8 - 13
sodium amide in ammonia
treating o-carborane with NaNH2 in liq. NH3, methylation (molar ratio carborane:metal=1:0.5, 1:1.0 and 1.1.5); various product ratio;;
参考文献
Stanko, V. I.; Gol'tyapin, Yu. V.
Journal of General Chemistry USSR (English Translation), 1971 , vol. 41, p. 2053 - 2058
Full Text Show Details
Gmelin Handbook: B: B-Verb.11, 4.1, page 56 - 59
