in solid matrix Irradiation (UV/VIS); Hg evapd. from liq. at 50°C; codeposited with D2 (2-8percent) and O2 (0.2-2.0percent) in excess Ar onto CsI window at 8 K; irradiated (mercury arc, >220 nm) for 15 min; annealed to 12 K; photolyzed for 20 min; annealed t o 14 K; photolyzed; monitored by IR spectra;
in solid matrix Irradiation (UV/VIS); Hg evapd. from liq. at 50°C; codeposited with D2 (2-8percent) and O2 (0.2-2.0percent) in excess Ne onto CsI window at 5 K for 1 h; irradiated (mercury arc, > 220 nm) for 25 min; annealed to 12 K; monitored by IR spectra;
in neat (no solvent) Kinetics; react. of H2-D2 over PMo12 at 573 K; initial pressures of H2: 12 Torr, D2 20 Torr; detn. of pressure decrease; evolved water detd. volumetrically;
参考文献
Mizuno, Noritaka; Watanabe, Tetsuji; Misono, Makoto
Journal of Physical Chemistry, 1990 , vol. 94, # 2 p. 890 - 894
iridium Kinetics; under ultra-high vac. for partial pressures of (15)NO and D2 between 5*10**-8 and 1*10**-6 Torr, total pressures between 10**-7 and 10**-6 Torr, and surface temp. between 300 and 1000 K;
参考文献
Ibbotson, D. E.; Wittrig, T. S.; Weinberg, W. H.
Surface Science, 1981 , vol. 111, p. 149 - 176
in solid matrix byproducts: (D2O)2; Irradiation (UV/VIS); Hg evapd. from liq. at 50°C; codeposited with O2 in excess D2 onto CsI window at 5 K for 30 min; irradiated (mercury arc, > 220 nm) for 42 min; monitored by IR spectra;
hydrogen in tetrahydrofuran byproducts: HD; THF soln. of (PPN)(Cr(CO)5(OAc)) stirred under H2/D2 (1:1) for 24 h at 125°C; not isolated; identified by IR and NMR;
参考文献
Tooley, Patricia A.; Ovalles, Cesar; Kao, S. C.; Darensbourg, Donald J.; Darensbourg, Marcetta Y.
Journal of the American Chemical Society, 1986 , vol. 108, # 18 p. 5465 - 5470
