4,4,4-三苯基-1-丁烯合成路线 （共 26 条）
反应条件
VCl2(N,N,N',N'-tetramethylethylenediamine)2; allyl bromide
1.) THF, 20 deg C, 1 h, 2.) 20 deg C, 1 h, reflux, 12 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kataoka, Yasutaka; Makihira, Isamu; Akiyama, Hiroaki; Tani, Kazuhide
Tetrahedron, 1997 , vol. 53, # 28 p. 9525 - 9540
反应条件
diethyl ether
anschliessendes Behandeln mit wss. HCl;
参考文献
Nesmejanow; Perewalowa
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1954 , p. 1002,1003; engl. Ausg. S. 873, 874
反应条件
VCl2(N,N,N',N'-tetramethylethylenediamine)2
1.) THF, 20 deg C, 1 h, 2.) 20 deg C, 1 h, reflux, 12 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kataoka, Yasutaka; Makihira, Isamu; Akiyama, Hiroaki; Tani, Kazuhide
Tetrahedron, 1997 , vol. 53, # 28 p. 9525 - 9540
反应条件
in benzene
1.5 h; Reflux;
参考文献
Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Organometallics, 2010 , vol. 29, # 20 p. 4562 - 4568
反应条件
in benzene
1.5 h; Reflux;
参考文献
Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Organometallics, 2010 , vol. 29, # 20 p. 4562 - 4568
反应条件
1: potassium trt-butoxide, butillithium / tetrahydrofuran; hexane / 2 h, -50 deg C, then 12 h, 0 deg C
2: 71 percent / O3 / CH2Cl2 / 1 h / -75 °C
View Scheme
参考文献
Moret, Etienne; Fuerrer, Juerg; Schlosser, Manfred
Tetrahedron, 1988 , vol. 44, # 12 p. 3539 - 3550
