in not given
byproducts: H(1+), H2O, O2; Electrolysis; at Cl(1-)/OH(1-)-ratio of 1:5; replacement of platinum electrodes with platinated electrodes or higher temps. decreases yield of chlorate;;
Maroni, J. C.; Authier-Cabibel, E.; Tremillon, B.
Bulletin de la Societe Chimique de France, 1959 , p. 127 - 131
Full Text Show Details
Gmelin Handbook: Cl: SVol.A, 143, page 328 - 330
Murray, R. L.; Kircher, M. S.
Trans. Electrochem. Soc., 1944 , vol. 86, p. 83 - 103
Full Text Show Details
Gmelin Handbook: Cl: SVol.A, 140, page 318 - 321
perchloric acid in water
Kinetics; Irradiation (UV/VIS); further intermediate: ClOH(1-); K2S2O8 and NaCl dissolved in water; pH adjusted by HClO4; solution photolyzed at 248 nm; at 297 K;
参考文献
Yu, Xiao-Ying; Bao, Zhen-Chuan; Barker, John R.
Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment, & General Theory, 2004 , vol. 108, # 2 p. 295 - 308
in water
Kinetics; byproducts: Cl; reacting sulfate radicals (produced by laser-flash photolysis of Na2S2O8) with Cl(1-) (11.4 - 35.0°C, different ionic strengths); monitoring reaction by UV spectroscopy;
参考文献
Huie, Robert E.; Clifton, Carol L.
Journal of Physical Chemistry, 1990 , vol. 94, # 23 p. 8561 - 8567
