sodium perchlorate in water
Kinetics; soln. of 2KHSO5*KHSO4*K2SO4 in H2O reacted with Cl(1-) (excess) in presence of NaClO4 at 25°C; not isolated; monitored by UV-vis spectra;
hydrogenchloride; sulfuric acid in water
Kinetics; oxidation of Cl(1-) by ozone catalyzed by acid (HCl/H2SO4) in the presence of NaCl, NaClO4 or KNO3 (different ionic strenght) at 24°C; mechanism discussed;
参考文献
Levanov; Kuskov; Zosimov; Antipenko; Lunin
Kinetics and Catalysis, 2003 , vol. 44, # 6 p. 740 - 746
in not given
Kinetics; byproducts: H2O; in acidic soln.;
参考文献
Liu, K. J.; Lester, H.; Peterson, N. C.
Inorganic Chemistry, 1966 , vol. 5, p. 2128 - 2131
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Gmelin Handbook: Mn: MVol.C2, 2.10.3.22.10.3, page 66 - 68
perchloric acid in water
Kinetics; Irradiation (UV/VIS); further intermediate: ClOH(1-); K2S2O8 and NaCl dissolved in water; pH adjusted by HClO4; solution photolyzed at 248 nm; at 297 K;
参考文献
Yu, Xiao-Ying; Bao, Zhen-Chuan; Barker, John R.
Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment, & General Theory, 2004 , vol. 108, # 2 p. 295 - 308
anatase O2Ti in water
Irradiation (UV/VIS); bubbled with oxygen in acidic or basic water;
参考文献
Herrmann, Jean-Marie; Pichat, Pierre
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1980 , vol. 76, p. 1138 - 1146
