ethyldimethylsilane; (Ace)Ru3(CO)7 in dichloromethane T=20°C; 6 h; Inert atmosphere;

lithium diisopropyl amide in ammonia Irradiation;

lithium amide in ammonia 2 h; Irradiation;

1: tert-butyl 2-methylpropionate With LiN(Cy)2 in toluene T=20°C; 0.25 h; Inert atmosphere; 2: bromobenzene With tris-(dibenzylideneacetone)dipalladium(0); N-[2'-(dicyclohexylphosphino)-1,1'-biphenyl-2-yl]-N,N-dimethylamine in toluene T=30°C; 2 h; Inert atmosphere;

ethyldimethylsilane; (Ace)Ru3(CO)7 in dichloromethane T=20°C; 6 h; Inert atmosphere;

ethyldimethylsilane; (Ace)Ru3(CO)7 in dichloromethane T=20°C; 6 h; Inert atmosphere;

in acetonitrile Irradiation; Yield given;