in hydrogen fluoride HF (liquid); Argon atmosphere, fluorocarbon polymer tube; various product ratio from various educt ratio; decantation, washing (HF);
参考文献
Journal of the American Chemical Society, , vol. 119, # 5 p. 1020 - 1026
SO2 in sulfur dioxide excess of SbF5 was kept with KPO2F2 in liq. SO2 at room temp. for several hours, under dry N2; SO2 and excess of SbF5 were pumped off, product was sublimed off at 95 °C, residue is KSbF6;
参考文献
Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 627, # 4 p. 631 - 637
in sulfur dioxide exclusion of air and moisture; 1. method: NMR-tube; SO2 and SbF5 alternate condensed to KPH2F4 at 77 K; melted off; shake at 205 K; 2.method: react. in two leg vessel; 1.method: KSbF6 pptd.; NMR-spectroscopy; 2.method: pptn. separated; solvent removed; Raman-spectroscopy of residue;
参考文献
Zeitschrift fuer Naturforschung, B: Chemical Sciences, , vol. 44, # 6 p. 679 - 682
in further solvent(s) exclusion of air and moisture; solvent: SO2ClF; SO2ClF and SbF5 alternate condensed to KPF6 in an NMR-tube at 77 K;; tube melted off; stored at 77 K; product not isolated; detected by NMR;
参考文献
Zeitschrift fuer Naturforschung, B: Chemical Sciences, , vol. 44, # 6 p. 679 - 682
