2-(2-溴苯基)-1-苯乙酮合成路线 （共 10 条）
反应条件
sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); [(t-Bu)3PH]BF4 in 1,4-dioxane T=60°C; 9 h;
参考文献
Willis, Michael C.; Taylor, Dawn; Gillmore, Adam T.
Tetrahedron, 2006 , vol. 62, # 49 p. 11513 - 11520
反应条件
nickel in ethylene glycol dimethyl ether T=85°C; 0.25 h;
参考文献
Inaba, Shin-ichi; Rieke, Reuben D.
Journal of Organic Chemistry, 1985 , vol. 50, # 9 p. 1373 - 1381
反应条件
mercury(II) diacetate; water in acetonitrile T=20°C; 0.416667 h;
参考文献
Farago, Janos; Kotschy, Andras
Synthesis, 2009 , # 1 p. 85 - 90
反应条件
1: SOCl2 / benzene / 2 h / Heating 2: AlCl3 / 2 h / Heating View Scheme
参考文献
Besandre, Ronald; Jaimes, Miguel; May, Jeremy A.
Organic Letters, 2013 , vol. 15, # 7 p. 1666 - 1669
反应条件
aluminium trichloride Friedel-Crafts acylation; 2 h; Heating;
参考文献
Besandre, Ronald; Jaimes, Miguel; May, Jeremy A.
Organic Letters, 2013 , vol. 15, # 7 p. 1666 - 1669
反应条件
1: With titanium tetrachloride; tert-butylamine in toluene T=120°C; 22 h; 2: With hydrogenchloride in toluene T=100°C; 24 h; Further stages. Title compound not separated from byproducts.;
参考文献
Ackermann, Lutz; Kaspar, Ludwig T.
Journal of Organic Chemistry, 2007 , vol. 72, # 16 p. 6149 - 6153
反应条件
(i) PCl3, (ii) /BRN= 969212/, AlCl3; Multistep reaction;
参考文献
Mulvaney,J.E.; Carr,L.J.
Journal of Organic Chemistry, 1968 , vol. 33, # 8 p. 3286 - 3291
反应条件
tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; IPr*HBF4 in o-xylene
24 h; HeatingInert atmosphere;
参考文献
Farago, Janos; Kotschy, Andras
Synthesis, 2009 , # 1 p. 85 - 90
反应条件
1: bis[2-(diphenylphosphino)phenyl] ether; palladium diacetate; potassium carbonate / N,N-dimethyl-formamide / 2 h / 120 °C / |Inert atmosphere
2: hydrogenchloride / tetrahydrofuran; water / 2 h / |Reflux
View Scheme
参考文献
Fei, Xiang-Dong; Tang, Ting; Ge, Zhi-Yuan; Zhu, Yong-Ming
Synthetic Communications, 2013 , vol. 43, # 24 p. 3262 - 3271
反应条件
1: toluene-4-sulfonic acid / toluene / |Dean-Stark; |Inert atmosphere; |Reflux
2: copper(l) iodide; K3PO4 / N,N-dimethyl-formamide / 110 °C / |Inert atmosphere
View Scheme
参考文献
Besandre, Ronald; Jaimes, Miguel; May, Jeremy A.
Organic Letters, 2013 , vol. 15, # 7 p. 1666 - 1669
