1: With azobisisobutyronitrile; tri-n-butyl-tin hydride in benzene
Rearrangement; 7.5 h;
2: With methyllithium in benzene
desilylation; Further stages.;
1: 2-acetyl-biphenyl With sodium tetrahydroborate in ethanol
T=20°C;
2: 2-acetyloxy-1-propene With lipase B from Candida antarctica (CAL-B) (Novoenzyme 435)
T=28°C; 240 h;
Huber et al.
Journal of the American Chemical Society, 1946 , vol. 68, p. 1109,1111
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Bradsher; Wert
Journal of the American Chemical Society, 1940 , vol. 62, p. 2806
1: [1-(2-bromophenyl)ethoxy]diphenylmethylsilane With azobisisobutyronitrile; tri-n-butyl-tin hydride in benzene
Rearrangement; 7.5 h;
2: methyllithium in benzene
desilylation; Further stages.;
