反式-1-庚烯-1-基硼酸频哪酯合成路线 (共 4 条)
反应条件
1: 1-n-heptyne With Br2BH-SMe2 in dichloromethane T=0°C; 2: With ammonium hydroxide; sodium hydroxide in dichloromethane 3: 2,3-dimethylbutane-2,3-diol in pentane T=20°C; Further stages.;
参考文献
Pietruszka, Joerg; Rieche, Anja C. M.; Wilhelm, Thorsten; Witt, Andreas
Advanced Synthesis and Catalysis, 2003 , vol. 345, # 12 p. 1273 - 1286
参考文献
N.V. ORGANON; PHARMACOPEIA INC.
Patent: WO2008/51826 A2, 2008 ;
Location in patent: Page/Page column 62; 63 ;
WO 2008/051826 A2
反应条件
magnesium sulfate in diethyl ether T=20°C; 1 h;
参考文献
Organic Letters, , vol. 6, # 3 p. 357 - 360
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2; triethylamine; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=25°C; 4 h; Inert atmosphere; regioselective reaction;
参考文献
Chemistry - A European Journal, , vol. 18, # 5 p. 1512 - 1521