(4-噻吩-2-苯基)甲醇合成路线 （共 55 条）
反应条件
magnesium; triphenylphosphine; palladium diacetate in tetrahydrofuran; ice-water
反应条件
Pd((CH3)2C6H3NC(CH3)CHC(CH3)NC6H3(CH3)2)(CH3)(P(CH2CH3)3); tetrabutylammomium bromide; sodium hydroxide in water T=60°C; Hiyama coupling; 12 h; Inert atmosphere;
参考文献
Chemical Communications, , vol. 46, # 47 p. 9046 - 9048
反应条件
bis(acetylacetonato) palladium; copper(l) iodide; 1,10-phenanthroline in 1-methyl-pyrrolidin-2-one; quinoline T=50 - 190°C; 0.25 h; Inert atmosphereMicrowave irradiation;
参考文献
Advanced Synthesis and Catalysis, , vol. 351, # 16 p. 2667 - 2674
反应条件
bis(acetylacetonate)nickel(II); IPr*HBF4 in tetrahydrofuran T=20°C; Inert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 74, # 24 p. 9566 - 9569
反应条件
1: thien-2-yl bromide With manganese in tetrahydrofuran T=20°C; 2 h; 2: 1-(iodo)-4-methylbenzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=20°C; 2 h;
参考文献
Tetrahedron Letters, , vol. 46, # 35 p. 5961 - 5964
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; [NiCl2(1,2-dimethoxyethane)]; caesium carbonate; zinc; tri-cyclo-hexyl-phosphine in ethylene glycol dimethyl ether; N,N-dimethyl-formamide T=20 - 60°C; Suzuki-Miyaura cross-coupling reaction; 36 h; Inert atmosphere; chemoselective reaction;
参考文献
Chemical Communications, , vol. 47, # 1 p. 307 - 309
反应条件
tetrabutylammomium bromide; potassium carbonate in water T=80°C; Suzuki-Miyaura coupling; 10 h;
参考文献
Organic and Biomolecular Chemistry, , vol. 10, # 23 p. 4531 - 4536
反应条件
palladium diacetate in ethylene glycol dimethyl ether T=60°C; 0.5 h;
参考文献
Synthetic Communications, , vol. 29, # 14 p. 2457 - 2465
反应条件
palladium diacetate in tetrahydrofuran T=20°C; Stille reaction; 1.5 h;
参考文献
Synthesis, , # 7 p. 1117 - 1122
反应条件
Pd bipyridyl anchored nanosized mesoporous silica MCM-41 in tetrahydrofuran T=50°C; Kumada-Corriu reaction; 3 h;
参考文献
Tetrahedron, , vol. 63, # 20 p. 4304 - 4309
