反式-1-苯基-1,3-丁二烯合成路线 (共 179 条)
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tetrahedron Letters, , vol. 24, # 37 p. 4029 - 4032
反应条件
titanium(IV) isopropylate; hydrogenchloride; isopropylmagnesium chloride 1.) ether, -78 deg C to -50 deg C, 0.5 h, -50 deg C to -40 deg C, 1.5 h; 2.) ether, -40 deg C to RT, 0.5-1 h; Yield given. Multistep reaction;
参考文献
Tetrahedron Letters, , vol. 37, # 49 p. 8865 - 8868
反应条件
1: 1.) CF3SO3H, 2.) ammonium chloride / 1.) THF, 0 deg C, 1 min 2: H(1+) View Scheme
参考文献
Tetrahedron Letters, , vol. 28, # 24 p. 2751 - 2752
反应条件
2: 1.) n-butyllithium(in hexane), 2.) tri-n-butylstannylmethyl iodide / 1.) THF, -78 deg C, 30 min, 2.) -78 deg C, 20 min and 0 deg C 1.5 h View Scheme
参考文献
Tetrahedron Letters, , vol. 23, # 21 p. 2205 - 2208
反应条件
1,4-dioxane; potassium hydroxide
参考文献
Zhurnal Obshchei Khimii, , vol. 27, p. 415,417; engl. Ausg. S. 469, 471
反应条件
diethyl ether; benzaldehyde
参考文献
Chemische Berichte, , vol. 87, p. 1318,1327
Org. Synth. Coll. Vol., , vol. V, p. 751
反应条件
iron(III) chloride in tetrahydrofuran T=10°C; 6 h; other catalysts; Product distribution;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 17, # 9 p. 1796 - 1797
Zhurnal Organicheskoi Khimii, , vol. 17, # 9 p. 2012 - 2013
反应条件
Fe(acetylacetonate)2 in tetrahydrofuran; diethyl ether T=15°C; 4.5 h; other temperature; other catalyst; Product distributionMechanism;
参考文献
Journal of Organic Chemistry USSR (English Translation), , p. 2157 - 2167
Zhurnal Organicheskoi Khimii, , vol. 19, # 12 p. 2465 - 2477
反应条件
Fe(acetylacetonate)2 in tetrahydrofuran; diethyl ether T=15°C; 4.5 h; other temperature; other catalyst; Product distributionMechanism;
参考文献
Journal of Organic Chemistry USSR (English Translation), , p. 2157 - 2167
Zhurnal Organicheskoi Khimii, , vol. 19, # 12 p. 2465 - 2477
反应条件
Yield given. Multistep reaction;
参考文献
Journal of Organic Chemistry, , vol. 63, # 13 p. 4181 - 4192