反式-1-苯基-1,3-丁二烯合成路线 (共 179 条)
反应条件
1: 3,5-bis(trifluoromethyl)phenyl methyl sulfone With potassium hydroxide in tetrahydrofuran 16 h; 2: (E)-cinnamaldehyde in tetrahydrofuran T=20°C; Julia-Kocienski methylenation; 16 h;
参考文献
Journal of Organic Chemistry, , vol. 70, # 16 p. 6404 - 6416
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; water; palladium diacetate in tetrahydrofuran T=50°C; Suzuki-Miyaura Coupling; 24 h; stereoselective reaction;
参考文献
Organic Letters, , vol. 14, # 1 p. 390 - 393
反应条件
Pd[P(o-tol)3]2 in tetrahydrofuran T=45°C; Stille coupling; 24 h; Inert atmosphere; optical yield given as percent destereoselective reaction;
参考文献
Chemical Communications, , vol. 48, # 69 p. 8661 - 8663
反应条件
1: in tetrahydrofuran T=0°C; 2: With acetyl chloride in tetrahydrofuran T=50°C; 1 h; 3: With potassium tert-butylate in tetrahydrofuran Heating;
参考文献
Tetrahedron Letters, , vol. 44, # 43 p. 8033 - 8036
反应条件
tetrabutyl ammonium fluoride; palladium dichloride in tetrahydrofuran T=65°C; Hiyama coupling; 8 h; stereoselective reaction;
参考文献
New Journal of Chemistry, , vol. 35, # 5 p. 1103 - 1110
反应条件
sulfuric acid in tetrahydrofuran 0.166667 h;
参考文献
Tetrahedron Letters, , vol. 23, # 44 p. 4589 - 4592
反应条件
sulfuric acid in tetrahydrofuran 0.166667 h;
参考文献
Tetrahedron Letters, , vol. 22, # 29 p. 2751 - 2752
反应条件
1: 1.) lithium diisopropylamide, 2.) triethylaluminum 2: p-toluenesulfonic acid View Scheme
参考文献
Journal of Organic Chemistry, , vol. 49, # 6 p. 1096 - 1104
反应条件
water; palladium diacetate; tri-cyclo-hexyl-phosphine in tetrahydrofuran T=50°C; Suzuki-Miyaura Coupling; 24 h; stereoselective reaction;
参考文献
Organic Letters, , vol. 14, # 1 p. 390 - 393
反应条件
PEPPSITM-IPr; potassium carbonate in tetrahydrofuran T=45°C; Stille coupling; 24 h; Inert atmosphere; optical yield given as percent destereoselective reaction;
参考文献
Chemical Communications, , vol. 48, # 69 p. 8661 - 8663