反式-1-苯基-1,3-丁二烯合成路线 （共 179 条）
反应条件
pyrrolidine; [PtCl2(η2:η2-cycloocta-1,5-diene)]; acetic acid; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in N,N-dimethyl-formamide T=60°C; 5 h; Inert atmosphereSchlenk techniqueMicrowave irradiation; regioselective reaction;
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 17 p. 4377 - 4381
Angew. Chem., , vol. 126, # 17 p. 4466 - 4470,5
反应条件
n-butyllithium; lithium iodide in tetrahydrofuran; hexane from 0 degC to room temp.;
参考文献
Tetrahedron Letters, , vol. 35, # 30 p. 5453 - 5456
反应条件
chloro-trimethyl-silane in tetrahydrofuran Methylenation;
参考文献
Synlett, , # 8 p. 1253 - 1254
反应条件
1: With N-bromosuccinmide in dichloromethane T=0 - 20°C; Inert atmosphereDarkness; 2: With 1,8-diazabicyclo[5.4.0]undec-7-ene in dichloromethane T=0 - 20°C; Inert atmosphereDarkness; optical yield given as percent destereoselective reaction;
参考文献
Organic Letters, , vol. 11, # 2 p. 465 - 468
反应条件
chloro-trimethyl-silane; dimethyl sulfoxide in acetonitrile T=50°C;
参考文献
Gazzetta Chimica Italiana, , vol. 122, # 10 p. 437 - 439
反应条件
iron(III) chloride; potassium carbonate in tetrahydrofuran T=10°C; 6 h;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 17, # 9 p. 1796 - 1797
Zhurnal Organicheskoi Khimii, , vol. 17, # 9 p. 2012 - 2013
反应条件
1: 62 percent / LiBr; acetic acid / palladium(II) acetate / 1 h / 40 °C 2: 56 percent / triethylamine; pinacolborane; DPEphos / palladium(II) acetate / dioxane; tetrahydrofuran / 5 h / 100 °C View Scheme
参考文献
Tetrahedron, , vol. 63, # 45 p. 10939 - 10948
反应条件
1: CuBr; diisopropylamine / dioxane / Heating 2: 62 percent / LiBr; acetic acid / palladium(II) acetate / 1 h / 40 °C 3: 56 percent / triethylamine; pinacolborane; DPEphos / palladium(II) acetate / dioxane; tetrahydrofuran / 5 h / 100 °C View Scheme
参考文献
Tetrahedron, , vol. 63, # 45 p. 10939 - 10948
反应条件
N,N-dimethyl-formamide dimethyl acetal in chloroform Ambient temperature;
参考文献
Chemische Berichte, , vol. 115, # 11 p. 3453 - 3469
反应条件
n-butyllithium; diethylzinc in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide; hexane
参考文献
Chemistry Letters, , p. 2029 - 2032
