Kinetics; byproducts: KCl, NaCl, Sn; N2, dry box; mech. activation in a vac. vibration mill, yields (82.5-92.5percent) depending on reagents ratio, weight of ball load, duration of mech.activation; IR, gas volumetry, X-ray powder diffraction;
参考文献
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 40, p. 1559 - 1562
Zhurnal Neorganicheskoi Khimii, , vol. 40, p. 1621 - 1624
aluminium trichloride in further solvent(s) (N2), powder of (NH4)2SO4 treated with soln. of NaBH4 in tetraglyme, stirred for 6 h at 140°C catalized by AlCl3;
参考文献
Li, Jun-Sheng; Zhang, Chang-Rui; Li, Bin; Cao, Feng; Wang, Si-Qing
European Journal of Inorganic Chemistry, 2010 , # 12 p. 1763 - 1766
in further solvent(s) byproducts: H2; under Ar atm.; grinded (NH4)2SO4 and NaBH4 stirred in triglyme heated to120°C for 30 min, treated at this temp. until the cease of gases released; mixt. distd. several times under high vac., collected in liq. N2 traps, condensed at -78°C; detd. by XRD, NMR, mass-spectrometry;
