in diethylene glycol byproducts: H2; N2; I2 in diglyme introduced at room temp. to generator flask contg. NaBH4 in diglyme; generated H2 and B2H6 bubbled through soln. of PhNEt2 in toluene or benzene of side tube at 0°C; excess B2H6 drifven off with stream of N2;
参考文献
Journal of Organometallic Chemistry, , vol. 323, p. 145 - 148
in water byproducts: H2, NaOH; pptn.; reaction mechanism discussed;;
参考文献
Mikheeva, V. I.; Ostrovityanova, S. E.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1966 , vol. 11, p. 1157 - 1158
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Gmelin Handbook: B: B-Verb.14, 3.9, page 117 - 119
in water to a soln. of pyridinium iodide in water (cooled in an ice bath) NaBH4 was added with stirring, mixt. stirred for 15 min at 0°C and 30 min at room temp.; extd. with ether, extract dried over Na2SO4 and evapd. to dryness; chromy. on silica gel column with CH2Cl2; elem. anal.;
参考文献
Gessner, Wieslaw; Brossi, Arnold
Synthetic Communications, 1985 , vol. 15, # 10 p. 911 - 916
