in ethanol byproducts: COD; 1 equiv. of NaBH4, 2 equiv. of phosphine per complex, room temp., few min, gas evolution; evapn., extn. (benzene), recrystn. (benzene/hexane);
in water aq. soln. of FeCl3 and NiCl2*6H2O mixed with aq. soln. of NaBH4, ppt. dried at 423 K, reduced with H2 at 873 K for 1 h; washed with H2O; elem. anal.;
参考文献
Vitta, Satish; Khuntia; Ravikumar; Bahadur
Journal of Magnetism and Magnetic Materials, 2008 , vol. 320, # 3-4 p. 182 - 189
in water aq. soln. of FeCl3 and NiCl2*6H2O mixed with aq. soln. of NaBH4, ppt. dried at 423 K, reduced with H2 at 873 K for 1 h; washed with H2O; elem. anal.;
参考文献
Vitta, Satish; Khuntia; Ravikumar; Bahadur
Journal of Magnetism and Magnetic Materials, 2008 , vol. 320, # 3-4 p. 182 - 189
in water in aqueous solns. at pH values from 4.32 to 9.91;
参考文献
Khain, V. S.; Volkov, A. A.; Martynova, V. F.
Inorganic Materials (Transl. of Neorg. Mater.), 1988 , vol. 24, p. 342 - 346
Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, 1988 , vol. 24, p. 423 - 426
in water byproducts: H2, H2O; pH 1-10; spectrophotometric monitoring;
参考文献
Khain, V. S.; Martynova, V. F.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1978 , vol. 23, p. 376 - 378
Zhurnal Neorganicheskoi Khimii, 1978 , vol. 23, p. 680 - 684
in diethyl ether
boiling (stirring, 4 h); water addn., separation of org. phase, drying over CaCl2, solvent evapn., distn. (vacuum);
参考文献
Boldyreva, N. A.; Andreev, A. A.; Komarov, N. V.
Journal of General Chemistry USSR (English Translation), 1988 , vol. 58, p. 1050 - 1051
Zhurnal Obshchei Khimii, 1988 , vol. 58, p. 1181 - 1181
