(OC-6-11)-六氟-锑酸铯合成路线 （共 25 条）
反应条件
byproducts: fluorine; melting at ca. 310°C; X-ray diffraction;
参考文献
Journal of Solid State Chemistry, , vol. 33, p. 283 - 288
反应条件
hydrogen fluoride in neat (no solvent)
byproducts: NF3; CsF and NF4SbF6 loading in the drybox, dry HF adding on the vacuum line, stirring for 15 min at 25°C, cooling to -78°C, NF4HF2 soln. filtering, UF6 condensing at -196°C onto the soln., stirring ambient temp., volatiles removing; identified by elem. anal., IR, NMR and Raman spectra;
参考文献
Wilson, William W.; Christe, Karl O.
Inorganic Chemistry, 1982 , vol. 21, p. 2091 - 2094
反应条件
HF in hydrogen fluoride
byproducts: NF3, HF; HF (liquid); dry CsF and NF4SbF6 were loaded in the drybox, dry HF was added, mixt. was stirred for 45 min at 25°C, then cooled to -78°C and the NF4HF2 soln. was filtered into the other half of the reactor, warmed to room temp., then cooled to -196.deg; ree.C and XeF6 was added, mixt. was warmed to room temp. and stirred for 12 h, volatiles were removed; NMR;
参考文献
Christe, Karl O.; Wilson, William W.
Inorganic Chemistry, 1982 , vol. 21, p. 4113 - 4117
反应条件
hydrogen fluoride in neat (no solvent)
byproducts: NF3; CsF and NF4SbF6 loading in the drybox, dry HF adding on the vacuum line, stirring for 15 min at 25°C, cooling to -78°C, NF4HF2 soln. filtering, WF6 condensing at -196°C onto the soln., warming to ambient temp., volatiles removing; identified by elem. anal., IR, NMR and Raman spectra;
参考文献
Wilson, William W.; Christe, Karl O.
Inorganic Chemistry, 1982 , vol. 21, p. 2091 - 2094
反应条件
in sulfur dioxide
byproducts: N2; liq. SO2 wasadded to mixt. of N5SbF6 and CsN3 in drybox at -196°C; mixt. was warmed to -64°C; volatiles removed at -64°C; pumped at room temp.;
参考文献
Dixon, David A.; Feller, David; Christe, Karl O.; Wilson, William W.; Vij, Ashwani; Vij, Vandana; Jenkins, H. Donald Brooke; Olson, Ryan M.; Gordon, Mark S.
Journal of the American Chemical Society, 2004 , vol. 126, # 3 p. 834 - 843
反应条件
in water
dissoln. of Sb2O3 in boiling aq. HF, addn. of CsF, further boiling (30 min); filtration while hot, concn., crystn. on cooling, recrystn. (aq. HF);
参考文献
Loss, Sandra; Roehr, Caroline
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1998 , vol. 53, # 1 p. 75 - 80
反应条件
hydrogen fluoride in hydrogen fluoride
byproducts: Kr, F2; -78°C;
参考文献
Christe, Karl O.; Wilson, William W.; Wilson, Richard D.
Inorganic Chemistry, 1984 , vol. 23, p. 2058 - 2063
反应条件
in neat (no solvent, solid phase)
at room temp. with large excess of HF; not isolated;
参考文献
Drake, Greg W.; Dixon, David A.; Sheehy, Jeffrey A.; Boatz, Jerry A.; Christe, Karl O.
Journal of the American Chemical Society, 1998 , vol. 120, # 33 p. 8392 - 8400
反应条件
hydrogen fluoride in hydrogen fluoride
addn. at -196°C, stirring at 20° C for 2 h; cooled to -78°C and filtered, most of HF removed by pumping, theresidue warmed to room temp., the volatiles pumped off (NF3 and HF), the solid residue contained CsSbF6;
参考文献
Christe, Karl O.; Wilson, William W.; Wilson, Richard D.
Inorganic Chemistry, 1980 , vol. 19, p. 1494 - 1498
反应条件
hydrogen fluoride in hydrogen fluoride
anh. HF added at -196°C, the mixt. kept at -78°C for 15 h, at -45°C for 2 h; CsSbF6 ppt. sepd. from NF4SClO4 soln., HF pumped off, the solid residuewarmed to room temp., de gaseous decompn. products sepd. by fractional condensation;
参考文献
Christe, Karl O.; Wilson, William W.; Wilson, Richard D.
Inorganic Chemistry, 1980 , vol. 19, p. 1494 - 1498
