carbon monoxide; hydrogen in 1,2,5-trimethyl-benzene byproducts: benzylalcohol; High Pressure; HMn(CO)5 was placed in an autoclave with benzaldehyde and mesitylene inpetroleum ether (40-60°C); sealed; was pressurized to 1200 psi with H2; CO added to a total pressure of 2400 psi; stirring; GLC; GC/MS;
参考文献
Sheeran, Daniel J.; Arenivar, John D.; Orchin, Milton
Journal of Organometallic Chemistry, 1986 , vol. 316, p. 139 - 146
in benzene-d6 Kinetics; byproducts: 9,10-dihydro-9,10-dimethylanthracene; distg. HMn(CO)5 into degassed benzene-d6 soln. of DMA; sealed under vac.; 82.3-110.6°C; further: also under 1 atm CO; react. followed by HNMR, gas chromy., IR;
参考文献
Sweany, Ray; Butler, Steven C.; Halpern, Jack
Journal of Organometallic Chemistry, 1981 , vol. 213, # 2 p. 487 - 492
in benzene-d6 Kinetics; byproducts: 9,10-dihydroanthracene; distg. HMn(CO)5 into degassed benzene-d6 soln. of anthracene; sealed under vac.; 100°C; react. followed by HNMR, gas chromy., IR;
参考文献
Sweany, Ray; Butler, Steven C.; Halpern, Jack
Journal of Organometallic Chemistry, 1981 , vol. 213, # 2 p. 487 - 492
