(CD3COCD3)D(1+) in gas T=57.9°C; experiment conditions: NBS pulsed ion cyclotron resonance; probability of a reactive H/D exchange encounter for the deuteronated ion as a function of the Gibbs free-energy change of the (endoergic) deuteron transfer reaction; Rate constantMechanismThermodynamic data;

in solid matrix Irradiation (UV/VIS); a sample of Ar/CH3SD co-deposited with a sample of Ar/CrCl2O2 onto a 14 K window, annealed to 36 K, irradiated for 1 h; not isolated, detected by IR;

W(001) Product distribution;

Ni(110) surface T=-133.1°C; Product distribution;

W(001) Product distribution;

Ni(110) surface T=-133.1°C; Product distribution;

W(001) Product distribution;