in tetrahydrofuran (N2); treatment of NaBH4 with ammonium salt in THF as in: Bonham, J.; Drago, R. S. Inorg. Synth. 1967, 9, 8; Noeth, H.; Beyer, H. Chem Ber. 1960, 93, 928; Kelly, H. C.; Marchelli, F. R.; Giusto, M. B. Inorg. Chem. 1964, 3, 431;

cis amino chloride T=24.9°C; ΔH; ΔS; MechanismKineticsRate constant;