potassium phenolate; oxygen in dimethyl sulfoxide

1: 53 percent / mercuric acetate / tetrahydrofuran / 19 h 2: 34 percent Chromat. / potassium phenoxide, oxygen (air) / dimethylsulfoxide; various solvent(s) View Scheme

CoA; adenosine 5'-triphosphoric acid; magnesium chloride in hydrogenchloride T=25°C; 0.5 h;

oxygen; rose bengal; adenosine 5'-triphosphoric acid; firefly luciferase in water T=25°C; pH=7.8; Kinetics; Further Variations:Reagents;

potassium phenolate; oxygen in dimethyl sulfoxide other solvent (THF), other base (t-BuOK), various pressure of oxygen; dependence of chemiluminescence quantum yield on oxygen pressure (relative to that at 760 mm O2); chemiluminescence spectra; reaction (nonchemiluminescent) in the absence of oxygen; Product distributionMechanismQuantum yield;