9-苄基-2,3,4,9-四氢-1H-咔唑合成路线 （共 28 条）
反应条件
trichlorophosphate
T=0°C;
参考文献
Murakami, Yasuoki; Yokoyama, Yuusaku; Miura, Tomoko; Nozawa, Sumiko; Takeda, Emiko; Suzuki, Hideharu
Heterocycles, 1988 , vol. 27, # 10 p. 2341 - 2344
反应条件
trichlorophosphate in N,N-dimethyl-formamide
T=0°C; 2.5 h; various molar ratios of POCl3; Product distributionMechanism;
参考文献
Murakami, Yasuoki; Yokoyama, Yuusaku; Okuyama, Naomi
Tetrahedron Letters, 1983 , vol. 24, # 21 p. 2189 - 2192
反应条件
trichlorophosphate
T=0°C;
参考文献
Murakami, Yasuoki; Yokoyama, Yuusaku; Miura, Tomoko; Nozawa, Sumiko; Takeda, Emiko; Suzuki, Hideharu
Heterocycles, 1988 , vol. 27, # 10 p. 2341 - 2344
反应条件
trichlorophosphate
T=120°C; Further byproducts given;
参考文献
Murakami, Yasuoki; Yokoyama, Yuusaku; Miura, Tomoko; Nozawa, Sumiko; Takeda, Emiko; Suzuki, Hideharu
Heterocycles, 1988 , vol. 27, # 10 p. 2341 - 2344
反应条件
trichlorophosphate in N,N-dimethyl-formamide
T=120°C; 2 h; Product distributionMechanism;
参考文献
Yokoyama, Yuusaku; Okuyama, Naomi; Iwadate, Shinji; Momoi, Tokuko; Murakami, Yasuoki
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 5 p. 1319 - 1329
反应条件
trichlorophosphate
T=120°C; with various formamides, 0 and 120 deg C; Product distribution;
参考文献
Murakami, Yasuoki; Yokoyama, Yuusaku; Miura, Tomoko; Nozawa, Sumiko; Takeda, Emiko; Suzuki, Hideharu
Heterocycles, 1988 , vol. 27, # 10 p. 2341 - 2344
反应条件
trichlorophosphate in N,N-dimethyl-formamide
T=120°C; 2 h; also reaction of 9-benzyl-1,2,3,4-tetrahydro-4-methylcarbazole; Product distributionMechanism;
参考文献
Yokoyama, Yuusaku; Okuyama, Naomi; Iwadate, Shinji; Momoi, Tokuko; Murakami, Yasuoki
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 5 p. 1319 - 1329
反应条件
1: 22 percent / POCl3 / 1 h / 120 °C
2: 2.) CrO3 in conc. H2SO4 (Jones reagent) / 1.) THF-hexane, -78 deg C, 30 min 2.) acetone, RT, 30 min
3: 70 percent / 1.5 h / 100 °C
4: 1.) NaBH4 2.) pyridine / 1.) ethanol, RT, 3 h 2.) RT, 2 d
View Scheme
参考文献
Yokoyama, Yuusaku; Okuyama, Naomi; Iwadate, Shinji; Momoi, Tokuko; Murakami, Yasuoki
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 5 p. 1319 - 1329
