6-溴-5-甲氧基吡啶甲酸甲酯合成路线 （共 7 条）
反应条件
in diethyl ether T=0°C;
参考文献
Kelly, T. Ross; Lang, Fengrui
Journal of Organic Chemistry, 1996 , vol. 61, # 14 p. 4623 - 4633
反应条件
4-(N,N-dimethlyamino)pyridine; triethylamine in dichloromethane Yield given;
参考文献
LUMIPHORE, INC.; MAGDA, Darren; XU, Jide; BUTLIN, Nathaniel, G.
Patent: WO2014/78690 A1, 2014 ;
Location in patent: Paragraph 00201 ;
反应条件
1: Br2 / pyridine / 77 h / Ambient temperature 2: 88 percent / K2CO3 / acetone / Heating 3: 77 percent / KMnO4 / H2O / 3 h / 90 °C 4: Et3N, DMAP / CH2Cl2 / 2 h / Ambient temperature View Scheme
参考文献
LUMIPHORE, INC.; MAGDA, Darren; XU, Jide; BUTLIN, Nathaniel, G.
Patent: WO2014/78690 A1, 2014 ;
反应条件
1: 77 percent / KMnO4 / H2O / 3 h / 90 °C 2: Et3N, DMAP / CH2Cl2 / 2 h / Ambient temperature View Scheme
参考文献
LUMIPHORE, INC.; MAGDA, Darren; XU, Jide; BUTLIN, Nathaniel, G.
Patent: WO2014/78690 A1, 2014 ;
反应条件
1: 88 percent / K2CO3 / acetone / Heating 2: 77 percent / KMnO4 / H2O / 3 h / 90 °C 3: Et3N, DMAP / CH2Cl2 / 2 h / Ambient temperature View Scheme
参考文献
LUMIPHORE, INC.; MAGDA, Darren; XU, Jide; BUTLIN, Nathaniel, G.
Patent: WO2014/78690 A1, 2014 ;
反应条件
aluminium trichloride; sodium chloride T=150°C; 0.0333333 h;
参考文献
Kelly, T. Ross; Lang, Fengrui
Journal of Organic Chemistry, 1996 , vol. 61, # 14 p. 4623 - 4633
反应条件
aluminium trichloride in dichloromethane 50 h; Heating;
参考文献
Kelly, T. Ross; Lang, Fengrui
Journal of Organic Chemistry, 1996 , vol. 61, # 14 p. 4623 - 4633
