2-(三甲基甲硅烷基)联苯合成路线 （共 13 条）
参考文献
Clark, H. A.; Gordon, A. F.; Young, C. W.; Hunter, M. J.
Journal of the American Chemical Society, 1951 , vol. 73, p. 3798 - 3803
Full Text View citing articles Show Details
Gmelin Handbook: Si: MVol.C, 28, page 86 - 90
反应条件
sodium in tetrahydrofuran
T=80°C; 24 h; chemoselective reaction;
参考文献
Iijima, Akinori; Amii, Hideki
Tetrahedron Letters, 2008 , vol. 49, # 41 p. 6013 - 6015
反应条件
1: 1-bromo-2-phenylbenzene With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 1 h;
2: chloro-trimethyl-silane in tetrahydrofuran; hexane
T=-78 - 20°C;
参考文献
Ball, Liam T.; Lloyd-Jones, Guy C.; Russell, Christopher A.
Journal of the American Chemical Society, 2014 , vol. 136, # 1 p. 254 - 264
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in ethanol; toluene
6 h; Heating;
参考文献
Kaufmann, Dieter
Chemische Berichte, 1987 , vol. 120, p. 901 - 906
反应条件
magnesium in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=80°C; 34 h;
参考文献
Gross, Ulrich; Kaufmann, Dieter
Chemische Berichte, 1987 , vol. 120, p. 991 - 994
反应条件
bis(acetylacetonate)nickel(II); 1,3-bis-(diphenylphosphino)propane in diethyl ether; toluene
Heating;
参考文献
Milburn, Robert R.; Snieckus, Victor
Angewandte Chemie - International Edition, 2004 , vol. 43, # 7 p. 888 - 891
反应条件
1: ortho-dibromobenzene With tert.-butyl lithium in tetrahydrofuran; diethyl ether; pentane
T=-120 - 20°C; 0.666667 h;
2: trimethylsilyl trifluoromethanesulfonate in tetrahydrofuran; diethyl ether; pentane
T=-120 - -110°C; 0.5 h; Further stages. Further byproducts.;
参考文献
Bettinger, Holger F.; Filthaus, Matthias
Journal of Organic Chemistry, 2007 , vol. 72, # 25 p. 9750 - 9752
反应条件
in benzene
T=225°C; 120 h;
参考文献
Birkofer, Leonhard; Wahle, Bernd
Chemische Berichte, 1983 , vol. 116, # 10 p. 3309 - 3315
反应条件
1: 93 percent / 30percent aq. H2O2 / acetic acid / 3 h / Ambient temperature
2: 95 percent / tetrahydrofuran / 0.5 h / -78 °C
3: 1) PhLi / 1) THF, -78 deg C, 30 min, 2) -20 deg C, 3 h
View Scheme
参考文献
Ogawa, Satoshi; Tajiri, Yoko; Furukawa, Naomichi
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 10 p. 3182 - 3184
反应条件
1: 65 percent / PhLi / tetrahydrofuran / 12 h / Heating
2: 93 percent / 30percent aq. H2O2 / acetic acid / 3 h / Ambient temperature
3: 95 percent / tetrahydrofuran / 0.5 h / -78 °C
4: 1) PhLi / 1) THF, -78 deg C, 30 min, 2) -20 deg C, 3 h
View Scheme
参考文献
Ogawa, Satoshi; Tajiri, Yoko; Furukawa, Naomichi
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 10 p. 3182 - 3184
