1,2,3,4-四氢-1H-芴合成路线 （共 29 条）
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran
参考文献
Smith, W. Kimmer; Hardin, Julie N.; Rabideau, Peter W.
Journal of Organic Chemistry, 1990 , vol. 55, # 18 p. 5301 - 5302
反应条件
toluene-4-sulfonic acid in benzene
Dehydration; Heating;
参考文献
Halterman, Ronald L.; Zhu, Chengian
Tetrahedron Letters, 1999 , vol. 40, # 42 p. 7445 - 7448
反应条件
1: CrO3
2: AlCl3 / petroleum ether / Heating
View Scheme
参考文献
Hodgkins,J.E. et al.
Journal of the American Chemical Society, 1964 , vol. 86, p. 4080 - 4085
反应条件
1: 1.) n-BuLi / 1.) THF, 3 h, 2.) 18 h
2: 1.) n-BuLi / 1.) THF
3: 94 percent / Li, NH3, t-BuOH / tetrahydrofuran / 0.5 h / -78 °C
4: 90 percent / 1.0 M tetrabutylammonium fluoride (TBAF) / tetrahydrofuran
View Scheme
参考文献
Smith, W. Kimmer; Hardin, Julie N.; Rabideau, Peter W.
Journal of Organic Chemistry, 1990 , vol. 55, # 18 p. 5301 - 5302
参考文献
Parham,W.E. et al.
Journal of the American Chemical Society, 1961 , vol. 83, p. 1751 - 1754
反应条件
1: 67 percent / tetrahydrofuran
2: Hydrobromic acid
View Scheme
参考文献
Canonne, Persephone; Foscolos, Georges B.; Belanger, Denis
Journal of Organic Chemistry, 1980 , vol. 45, # 10 p. 1828 - 1835
反应条件
1: 67 percent / tetrahydrofuran
2: Hydrobromic acid
View Scheme
参考文献
Canonne, Persephone; Foscolos, Georges B.; Belanger, Denis
Journal of Organic Chemistry, 1980 , vol. 45, # 10 p. 1828 - 1835
反应条件
1: 94 percent / Li, NH3, t-BuOH / tetrahydrofuran / 0.5 h / -78 °C
2: 90 percent / 1.0 M tetrabutylammonium fluoride (TBAF) / tetrahydrofuran
View Scheme
参考文献
Smith, W. Kimmer; Hardin, Julie N.; Rabideau, Peter W.
Journal of Organic Chemistry, 1990 , vol. 55, # 18 p. 5301 - 5302
反应条件
1: 1.) n-BuLi / 1.) THF
2: 94 percent / Li, NH3, t-BuOH / tetrahydrofuran / 0.5 h / -78 °C
3: 90 percent / 1.0 M tetrabutylammonium fluoride (TBAF) / tetrahydrofuran
View Scheme
参考文献
Smith, W. Kimmer; Hardin, Julie N.; Rabideau, Peter W.
Journal of Organic Chemistry, 1990 , vol. 55, # 18 p. 5301 - 5302
反应条件
1: 74 percent / chromium(II) chloride; nickel cloride / dimethylformamide
2: 87 percent / p-toluenesulfonic acid / benzene / Heating
View Scheme
参考文献
Halterman, Ronald L.; Zhu, Chengian
Tetrahedron Letters, 1999 , vol. 40, # 42 p. 7445 - 7448
