5,5'-二溴-3,3'-二己基-2,2'-并噻吩合成路线 （共 5 条）
反应条件
N-bromosuccinmide in chloroform; acetic acid 0.5 h; Heating;
参考文献
Higuchi, Hiroyuki; Nakayama, Taketoshi; Koyama, Haruki; Ojima, Juro; Wada, Tatsuo; Sasabe, Hiroyuki
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 8 p. 2363 - 2378
反应条件
N-bromosuccinmide in chloroform; acetic acid 0.5 h;
参考文献
Higuchi, Hiroyuki; Nakayama, Taketoshi; Koyama, Haruki; Ojima, Juro; Wada, Tatsuo; Sasabe, Hiroyuki
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 8 p. 2363 - 2378
反应条件
1: 352 mg / 1.) butyllithium, 2.) Fe(acac)3 / 1.) THF, hexane, 20 min, 2.) THF, hexane, -70 deg C, 2 h 2: 32 percent / NBS / CHCl3; acetic acid / 0.5 h View Scheme
参考文献
Higuchi, Hiroyuki; Nakayama, Taketoshi; Koyama, Haruki; Ojima, Juro; Wada, Tatsuo; Sasabe, Hiroyuki
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 8 p. 2363 - 2378
反应条件
1: 88 percent / NBS / CHCl3; acetic acid / 0.5 h 2: 352 mg / 1.) butyllithium, 2.) Fe(acac)3 / 1.) THF, hexane, 20 min, 2.) THF, hexane, -70 deg C, 2 h 3: 32 percent / NBS / CHCl3; acetic acid / 0.5 h View Scheme
参考文献
Higuchi, Hiroyuki; Nakayama, Taketoshi; Koyama, Haruki; Ojima, Juro; Wada, Tatsuo; Sasabe, Hiroyuki
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 8 p. 2363 - 2378
反应条件
N-bromosuccinmide; n-butyllithium; iron (III) acetylacetonate 1.) THF, -40 deg C, 2.) 20 deg C; Multistep reaction;
参考文献
Higuchi, Hiroyuki; Hayashi, Noriyuki; Koyama, Haruki; Ojima, Juro
Chemistry Letters, 1995 , # 12 p. 1115 - 1116
