二甲基3-(氰基甲l烯)戊烷二酸酯合成路线 （共 6 条）
反应条件
ammonium acetate; acetic acid in benzene 24 h; Reflux;
参考文献
Canadillas-Delgado, Laura; Martin, Tomas; Fabelo, Oscar; Pasan, Jorge; Delgado, Fernando S.; Lloret, Francesc; Julve, Miguel; Ruiz-Perez, Catalina
Chemistry - A European Journal, 2010 , vol. 16, # 13 p. 4037 - 4047
反应条件
sodium hydroxide in ethanol
参考文献
Curran, Dennis P.; Liu, Hui
Journal of the American Chemical Society, 1992 , vol. 114, # 14 p. 5863 - 5864
反应条件
1: 95 percent / NaOH / ethanol 2: 1.) PCl5, 2.) HBr gas 3: 70 percent / NaH, LiBr / 1,2-dimethoxy-ethane View Scheme
参考文献
Curran, Dennis P.; Liu, Hui
Journal of the American Chemical Society, 1992 , vol. 114, # 14 p. 5863 - 5864
反应条件
1: KOH / ethanol / 48 h / 0 °C 2: PCl5 / CH2Cl2 / 9 h / 25 °C 3: 1.) HBr / 1.) CH2Cl2, a) -78 deg C, 1 h, b) RT, 8 h, 2.) CH2Cl2, RT, 2 h View Scheme
参考文献
Curran, Dennis P.; Liu, Hui
Journal of the American Chemical Society, 1992 , vol. 114, # 14 p. 5863 - 5864
反应条件
5-palladium/activated carbon in methanol T=20°C; 96 h;
参考文献
Canadillas-Delgado, Laura; Martin, Tomas; Fabelo, Oscar; Pasan, Jorge; Delgado, Fernando S.; Lloret, Francesc; Julve, Miguel; Ruiz-Perez, Catalina
Chemistry - A European Journal, 2010 , vol. 16, # 13 p. 4037 - 4047
反应条件
1: KOH / ethanol / 48 h / 0 °C
2: PCl5 / CH2Cl2 / 9 h / 25 °C
4: 10 percent / H+ / dioxane / 17 h / 96 °C
View Scheme
参考文献
Curran, Dennis P.; Liu, Hui; Josien, Hubert; Ko, Sung-Bo
Tetrahedron, 1996 , vol. 52, # 35 p. 11385 - 11404
