4-甲氧基苯硼酸频那醇酯合成路线 （共 109 条）
反应条件
potassium acetate; palladium diacetate in 1,4-dioxane T=110°C; 0.166667 h;
参考文献
GENENTECH, INC.; SUMITOMO CHEMICAL COMPANY, LIMITED
Patent: US2012/123122 A1, 2012 ;
Location in patent: Page/Page column 13 ;
反应条件
tert.-butylnitrite; dibenzoyl peroxide in acetonitrile T=20°C; Sandmeyer reaction; 2 h;
参考文献
PEKING UNIVERSITY
Patent: US2012/184768 A1, 2012 ;
Location in patent: Page/Page column 2 ;
反应条件
copper(l) iodide; palladium diacetate; caesium carbonate; triphenylphosphine in acetonitrile T=20°C; Miyaura Borylation Reaction; 24 h; chemoselective reaction;
参考文献
Ratniyom, Jadsada; Dechnarong, Nattanee; Yotphan, Sirilata; Kiatisevi, Supavadee
European Journal of Organic Chemistry, 2014 , vol. 2014, # 7 p. 1381 - 1385
反应条件
SIDip*HCl; palladium diacetate in tetrahydrofuran T=20°C; 1 h;
参考文献
Ma, Yudao; Song, Chun; Jiang, Wei; Xue, Guoping; Cannon, John F.; Wang, Xiaomei; Andrus, Merritt B.
Organic Letters, 2003 , vol. 5, # 24 p. 4635 - 4638
反应条件
palladium diacetate; triethylamine; bis[2-(diphenylphosphino)phenyl] ether in tetrahydrofuran; 1,4-dioxane T=100°C; 4 h;
参考文献
Broutin, Pierre-Emmanuel; Cerna, Igor; Campaniello, Maria; Leroux, Frederic; Colobert, Francoise
Organic Letters, 2004 , vol. 6, # 24 p. 4419 - 4422
反应条件
C37H51ClFeNPPd; potassium acetate in 1,4-dioxane T=80°C; Suzuki-Miyaura coupling; 3 h; Inert atmosphere;
参考文献
Wang, Lianhui; Li, Jingya; Cui, Xiuling; Wu, Yusheng; Zhu, Zhiwu; Wu, Yangjie
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 11-12 p. 2002 - 2010
反应条件
1: tBuCH2CH2B(H)NiPr2; 4-methoxybenzenediazonium tetrafluoroborate With biscyclopentadienyliron(II) in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; SolventReagent/catalystConcentration;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 55-56 ;
反应条件
in diethyl ether T=20°C; 4 h; Reagent/catalystSolvent;
参考文献
UNIVERSITE DE BORDEAUX I; Centre National de la Recherche Scientifique; Pucheault, Mathieu Jonathan Damien; Marciasini, Ludovic Daniel Alain; Vaultier, Michel
Patent: EP2684887 A1, 2014 ;
Location in patent: Paragraph 0108; 0109; 0110; 0111 ;
反应条件
1: With triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in 1,4-dioxane T=80°C; 18 h; 2: 4-methoxybenzenediazonium tetrafluoroborate; 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane in 1,4-dioxane T=80°C; 18 h;
参考文献
US6680401 B1, ;
Page column 65 ;
反应条件
1: 4-methoxy-aniline With boron trifluoride diethyl etherate; isopentyl nitrite in acetonitrile T=0°C; 0.333333 h; 2: tBuCH2CH2B(H)NiPr2 in acetonitrile T=20°C; 3 h; 3: 2,3-dimethylbutane-2,3-diol With methanol in acetonitrile T=20°C; 5 h;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 51-52 ;
