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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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4-氟三丁基甲锡烷基苯
合成路线
（共 35 条）
1461-22-9
三丁基氯化锡
+
460-00-4
对溴氟苯
→
反应条件
17151-47-2
4-氟三丁基甲锡烷基苯
反应条件
1: 1-bromo-4-fluorobenzene With tert.-butyl lithium in diethyl ether; pentane T=-78°C; 0.5 h; 2: tributyltin chloride in diethyl ether; pentane T=23°C; 1 h;
参考文献
PRESIDENT AND FELLOWS OF HARVARD COLLEGE; RITTER, Tobias; FURUYA, Takeru; TANG, Pingping
Patent: WO2010/59943 A2, 2010 ;
Location in patent: Page/Page column 33 ;
352-34-1
对氟碘苯
+
1461-22-9
三丁基氯化锡
→
反应条件
17151-47-2
4-氟三丁基甲锡烷基苯
反应条件
in diethyl ether refluxing, 9h;;
参考文献
Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.5.6, page 318 - 322
17151-47-2
4-氟三丁基甲锡烷基苯
+
98-58-8
对溴苯磺酰氯
→
反应条件
398-21-0
4-溴-4′-氟联苯
反应条件
tris-(dibenzylideneacetone)dipalladium(0); copper(I) bromide dimethylsulfide complex; trifuran-2-yl-phosphane in tetrahydrofuran Stille coupling; 6 h; Heating;
参考文献
Dubbaka, Srinivas Reddy; Vogel, Pierre
Journal of the American Chemical Society, 2003 , vol. 125, # 50 p. 15292 - 15293
17151-47-2
4-氟三丁基甲锡烷基苯
+
96898-10-1
→
反应条件
352-67-0
4-三氟甲氧基氟苯
反应条件
1: With trifluoromethanesulfonic acid trifluoromethyl ester; tris(dimethylamino)-sulphonium difluorotrimethylsilicate; sodium hydrogencarbonate in tetrahydrofuran T=-50°C; Inert atmosphere; 2: With AgPF6; F-TEDA-PF6 in tetrahydrofuran; acetone T=-50 - 23°C; Inert atmosphereDarkness;
参考文献
Huang, Chenghong; Liang, Theresa; Harada, Shinji; Lee, Eunsung; Ritter, Tobias
Journal of the American Chemical Society, 2011 , vol. 133, # 34 p. 13308 - 13310
3582-05-6
三氟乙基三氟甲烷磺酸酯
+
17151-47-2
4-氟三丁基甲锡烷基苯
→
反应条件
462-06-6
氟苯
+
352-67-0
4-三氟甲氧基氟苯
反应条件
1: With sodium hydrogencarbonate in tetrahydrofuran T=-30°C; Inert atmosphere; 2: With AgPF6; F-TEDA-PF6 in tetrahydrofuran; acetone T=-30 - 23°C; Inert atmosphereDarkness;
参考文献
Journal of the American Chemical Society, , vol. 133, # 34 p. 13308 - 13310
3582-05-6
三氟乙基三氟甲烷磺酸酯
+
17151-47-2
4-氟三丁基甲锡烷基苯
→
反应条件
540-36-3
1,4-二氟苯
+
352-67-0
4-三氟甲氧基氟苯
反应条件
1: With tetramethyl-ammonium fluoride; sodium hydrogencarbonate in tetrahydrofuran T=-30°C; Inert atmosphere; 2: With AgPF6; F-TEDA-PF6 in tetrahydrofuran; acetone T=-30 - 23°C; Inert atmosphereDarkness;
参考文献
Journal of the American Chemical Society, , vol. 133, # 34 p. 13308 - 13310
17151-47-2
4-氟三丁基甲锡烷基苯
+
96898-10-1
→
反应条件
462-06-6
氟苯
+
371-41-5
4-氟苯酚
+
352-67-0
4-三氟甲氧基氟苯
反应条件
1: With trifluoromethanesulfonic acid trifluoromethyl ester; sodium hydrogencarbonate in tetrahydrofuran T=-30°C; Inert atmosphere; 2: With silver nitrate; F-TEDA-PF6 in tetrahydrofuran; acetone T=-30 - 23°C; Inert atmosphereDarkness;
参考文献
Journal of the American Chemical Society, , vol. 133, # 34 p. 13308 - 13310
17151-47-2
4-氟三丁基甲锡烷基苯
→
反应条件
398-23-2
4,4'-二氟联苯
反应条件
(tBuCN)2CuOTf; 1-Fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate in ethyl acetate T=25°C; 12 h; Inert atmosphereGlovebox; Solvent;
参考文献
Journal of the American Chemical Society, , vol. 135, # 12 p. 4648 - 4651
17151-47-2
4-氟三丁基甲锡烷基苯
→
反应条件
540-36-3
1,4-二氟苯
+
398-23-2
4,4'-二氟联苯
反应条件
(tBuCN)2CuOTf; 1-Fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate in dichloromethane T=25°C; 12 h; Inert atmosphereGlovebox; Solvent;
参考文献
Journal of the American Chemical Society, , vol. 135, # 12 p. 4648 - 4651
67-56-1
甲醇
+
17151-47-2
4-氟三丁基甲锡烷基苯
→
反应条件
462-06-6
氟苯
+
459-60-9
4-氟苯甲醚
+
540-36-3
1,4-二氟苯
反应条件
sodium trifluoro-methanesulfonate; sodium hydrogencarbonate; F-TEDA-PF6; silver(l) oxide in acetone T=65°C; 5 h; Sealed vialInert atmosphere;
参考文献
Tang, Pingping; Furuya, Takeru; Ritter, Tobias
Journal of the American Chemical Society, 2010 , vol. 132, # 34 p. 12150 - 12154
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