二苯基(三甲基硅基)膦合成路线 （共 101 条）
反应条件
bis(benzonitrile)palladium(II) dichloride in toluene Substitution; 26 h; Heating;
参考文献
Trost, Barry M.; Bunt, Richard C.; Lemoine, Remy C.; Calkins, Trevor L.
Journal of the American Chemical Society, 2000 , vol. 122, # 25 p. 5968 - 5976
参考文献
Kellner,K. et al.
Journal of Organometallic Chemistry, 1978 , vol. 149, p. 167 - 176
反应条件
potassium hydroxide; TMSI; Pd(CHCN)2Cl2 in methanol; ethanol; water; ethyl acetate; benzene
参考文献
Stanford University
Patent: US5739396 A1, 1998 ;
反应条件
dichloro bis(acetonitrile) palladium(II) in benzene T=50°C; 53 h;
参考文献
Tunney, S. E.; Stille, J. K.
Journal of Organic Chemistry, 1987 , vol. 52, # 5 p. 748 - 753
反应条件
[NiCl2(PPh3)2]; potassium tert-butylate in 1,4-dioxane T=90°C; 10 h; Inert atmosphere;
参考文献
Sun, Meng; Zhang, Hong-Yu; Han, Qi; Yang, Kuo; Yang, Shang-Dong
Chemistry - A European Journal, 2011 , vol. 17, # 35 p. 9566 - 9570
反应条件
[NiCl2(PPh3)2]; potassium tert-butylate in 1,4-dioxane T=90°C; 10 h; Inert atmosphere;
参考文献
Sun, Meng; Zhang, Hong-Yu; Han, Qi; Yang, Kuo; Yang, Shang-Dong
Chemistry - A European Journal, 2011 , vol. 17, # 35 p. 9566 - 9570
反应条件
Mn(CO)5Cl in toluene byproducts: CO, [Mn2(CO)8((C6H5)2P)Cl], (CH3)3SiCl; reaction of toluene soln. of Mn(CO)5I with equimolar amt. of ligand for1.5 h under N2; addn. of Mn(CO)5Cl; storage of soln. for 3 h at ambienttemp.; heating to 80°C for 10 min; removal of solvent in vac.; dissolving residue in CH2Cl2; TLC with petrol/chloroform;
参考文献
Manning, Peter J.; Peterson, Louis K.; Wada, Fumio; Dhami, Randi S.
Inorganica Chimica Acta, 1986 , vol. 114, p. 15 - 20
反应条件
in acetonitrile
48 h; Ambient temperature;
参考文献
Kochetkov; Efimova; Trostyanskaya; Kazankova; Beletskaya
Russian Chemical Bulletin, 1998 , vol. 47, # 9 p. 1744 - 1748
反应条件
1: diethyl ether / -60 °C
2: aq. NaOH
3: aq. NaOH
View Scheme
参考文献
Angelova, Olyana; Kirilov, Emil M. G.; Kirilov, Marko; Petrov, Galin; Kaneti, Jose; Macicek, Josef
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 1405 - 1408
反应条件
[NiCl2(PPh3)2]; potassium tert-butylate in 1,4-dioxane
T=90°C; 10 h; Inert atmosphere;
参考文献
Sun, Meng; Zhang, Hong-Yu; Han, Qi; Yang, Kuo; Yang, Shang-Dong
Chemistry - A European Journal, 2011 , vol. 17, # 35 p. 9566 - 9570
