1,2-双(2,4-二甲基-5-苯基-3-噻吩基)-3,3,4,4,5,5-六氟-1-环戊烯合成路线 （共 8 条）
反应条件
1: 2,4-dimethyl-5-phenyl-3-bromothiophene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 2: 1,2,3,3,4,4,5,5-octafluorocyclopentene in tetrahydrofuran; hexane T=-78°C; Further stages.;
参考文献
De Meijere, Armin; Ligang, Zhao; Belov, Vladimir N.; Bossi, Mariano; Noltemeyer, Matthias; Hell, Stefan W.
Chemistry - A European Journal, 2007 , vol. 13, # 9 p. 2503 - 2516
反应条件
2: 77 percent / I2, HIO3 / CCl4; acetic acid; H2O / 2 h / Heating 3: 1) n-BuLi / 1) THF, hexane, 1 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 60, # 25 p. 8305 - 8309
反应条件
2: 77 percent / I2, HIO3 / CCl4; acetic acid; H2O / 2 h / Heating 3: 1) n-BuLi / 1) THF, hexane, 1 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 60, # 25 p. 8305 - 8309
反应条件
1: 77 percent / I2, HIO3 / CCl4; acetic acid; H2O / 2 h / Heating 2: 1) n-BuLi / 1) THF, hexane, 1 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 60, # 25 p. 8305 - 8309
反应条件
1: 2,4-dimethyl-5-phenyl-3-bromothiophene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.666667 h; Inert atmosphere; 2: 1-(2,4-dimethyl-5-phenyl-3-thienyl)heptafluorocyclopentene in tetrahydrofuran; hexane T=-78°C; 3 h; Inert atmosphere;
参考文献
Journal of Materials Chemistry, , vol. 21, # 43 p. 17249 - 17258
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere 1.2: 1.5 h / -78 °C / Inert atmosphere 2.1: n-butyllithium / tetrahydrofuran; hexane / 0.67 h / -78 °C / Inert atmosphere 2.2: 3 h / -78 °C / Inert atmosphere View Scheme
参考文献
Journal of Materials Chemistry, , vol. 21, # 43 p. 17249 - 17258
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere 1.2: 1.5 h / -78 °C / Inert atmosphere 2.1: n-butyllithium / tetrahydrofuran; hexane / 0.67 h / -78 °C / Inert atmosphere 2.2: 3 h / -78 °C / Inert atmosphere View Scheme
参考文献
Journal of Materials Chemistry, , vol. 21, # 43 p. 17249 - 17258
反应条件
n-butyllithium 1) THF, hexane, 1 h; Yield given. Multistep reaction;
参考文献
Journal of Organic Chemistry, , vol. 60, # 25 p. 8305 - 8309
