1: 71 percent / Ti(OEt)4 2: L-Selectride / tetrahydrofuran / 3 h / 0 - 20 °C 3: 98 percent / HCl / dioxane / 20 °C View Scheme
参考文献
Colyer, John T.; Andersen, Neil G.; Tedrow, Jason S.; Soukup, Troy S.; Faul, Margaret M.
Journal of Organic Chemistry, 2006 , vol. 71, # 18 p. 6859 - 6862
1: L-Selectride / tetrahydrofuran / 3 h / 0 - 20 °C 2: 98 percent / HCl / dioxane / 20 °C View Scheme
参考文献
Colyer, John T.; Andersen, Neil G.; Tedrow, Jason S.; Soukup, Troy S.; Faul, Margaret M.
Journal of Organic Chemistry, 2006 , vol. 71, # 18 p. 6859 - 6862
NaPF6; 1,3,5-Tris{[(S,S)-4,5-diphenyl-2-oxazolinyl]methyl}-2,4,6-trimethylbenzene in water-d2; chloroform-d1 T=25°C; Resolution of racemate; optical yield given as percent ee;
参考文献
Kim, Sung-Gon; Sambasivan, Sunderraman; Ann, Kyo Han
Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 3 p. 724 - 726
1: benzoic acid With 1,1'-carbonyldiimidazole in neat (no solvent)
0.0833333 h; Milling;
2: (S)-(-)-α-methylbenzylamine hydrochloride in neat (no solvent)
0.166667 h; Milling;
