1,3 -双( 2,4,6 -三甲苯基)氯化咪唑鎓合成路线 (共 6 条)
反应条件
1: N,N'-di(2,4,6-trimethylphenyl)-4,5-dihydroimidazolinium chloride With potassium 2-methyl-2-butoxide in hexane; toluene T=50°C; 0.166667 h; 2: Fuuml;rstner's ruthenium indenylidene catalyst in hexane; toluene T=50°C; 18 h;
参考文献
Puentener, Kurt; Scalone, Michelangelo
Patent: US2006/241156 A1, 2006 ;
Location in patent: Page/Page column 6 ;
反应条件
KO(C(CH3)3) in hexane byproducts: KCl, C(CH3)3OH, PCy3; using Schlenk techniques; mixing of (Mes2C3N2H5)(Cl), KO(t-Bu) and (PCy3)2Cl2Ru(CHPh) in anhyd. hexane; degassing of soln. by pulling vac. for afew minutes, heating at 60°C for 24 h in vac. with very vigorous stirring; cooling to room temp., opening the flask to air, addn. of 1:1 2-propanol:water; stirring in air for 30 min, filtration, washing with 2-propanol:water and with hexane, drying under vac. overnight, elem. anal.;
参考文献
Trnka, Tina M.; Morgan, John P.; Sanford, Melanie S.; Wilhelm, Thomas E.; Scholl, Matthias; Choi, Tae-Lim; Ding, Sheng; Day, Michael W.; Grubbs, Robert H.
Journal of the American Chemical Society, 2003 , vol. 125, # 9 p. 2546 - 2558
反应条件
potassium hydride in tetrahydrofuran
T=25°C; 3 h;
参考文献
Arduengo III, Anthony J.; Krafczyk, Roland; Schmutzler, Reinhard; Craig, Hugh A.; Goerlich, Jens R.; Marshall, William J.; Unverzagt, Markus
Tetrahedron, 1999 , vol. 55, # 51 p. 14523 - 14534
反应条件
potassium hydroxide
T=60°C; 1.25 h;
参考文献
Trnka, Tina M.; Morgan, John P.; Sanford, Melanie S.; Wilhelm, Thomas E.; Scholl, Matthias; Choi, Tae-Lim; Ding, Sheng; Day, Michael W.; Grubbs, Robert H.
Journal of the American Chemical Society, 2003 , vol. 125, # 9 p. 2546 - 2558
反应条件
in methanol; chloroform
参考文献
Grubbs, Robert H.; Moore, Jason L.; Morgan, John P.; Bell, Andrew
Patent: US2003/83445 A1, 2003 ;
反应条件
potassium hydride in tetrahydrofuran
T=25°C; 1 h;
参考文献
Csihony, Szilard; Culkin, Darcy A.; Sentman, Alan C.; Dove, Andrew P.; Waymouth, Robert M.; Hedrick, James L.
Journal of the American Chemical Society, 2005 , vol. 127, # 25 p. 9079 - 9084